张科课题组介绍
张科,助理教授、研究员 通讯地址:4号楼103 电子邮件:zhangke2@shanghaitech.edu.cn 个人简历: 2005-2009 浙江大学 材料系,本科 2009-2012 中国科学院上海光学精密机械研究所,硕士 2012-2013 国家开发银行,职员 2014-2017 德国马克斯普朗克学会Fritz-Haber研究所/柏林工业大学,博士 2017-2018 瑞士洛桑联邦理工学院 物理系,博士后 2018-2019 德国慕尼黑工业大学 化学系, 博士后 2020-2024 丹麦科技大学 物理系,博士后 2024年5月 丹麦科技大学 物理系,高级研究员 2024年8月 上海科技大学 物质科学与技术学院,助理教授,研究员,PI |
本课题组致力于团簇和纳米颗粒对能源相关小分子的精准催化转化研究。通过超高真空质量选择团簇束流技术,以原子精度制备尺寸从单原子到10nm范围内的单分散样品,配合自主开发的超高真空兼容高灵敏度常压反应器和原位谱学/显微学表征手段,定量建立催化剂纳米颗粒催化过程的构-效、组-效关系。
基于上述实验技术和研究方法,课题组的具体研究方向为:
团簇拟酶催化:包括对Mo-Fe固氮酶等的原子精确合成和模型催化测试
单颗粒原位动态催化过程
纳米颗粒和团簇的限域催化效应
温和条件合成氨的模型催化研究
本课题组长期诚聘博士后研究员、硕博连读研究生,待遇优厚,工作环境优越。欢迎对超高真空技术和原创性科学仪器开发有兴趣,动手能力强,有志于在能源相关小分子催化转化,团簇化学等领域开展最前沿研究的学生学者加入!有意者请直接与PI邮件联系。
# Equal contribution,* Corresponding author 1. Zhang, K.#, Cao, A.#, Wandall, L. H., Vernieres, J., Kibsgaard, J., Nørskov, J* & Chorkendorff, I*. (2024). Spin-mediated promotion of Co catalysts for ammonia synthesis. Science, 6689(383), 1357 2. Fu, X., Niemann, V. A., Zhou, Y., Li, S., Zhang, K., Pedersen, J. B., et al., Chorkendorff, I*. (2024). Calcium-mediated nitrogen reduction for electrochemical ammonia synthesis. Nature Materials, 23(1), 101-107 3. Zhang, K.*, Wandall, L. H., Vernieres, J., Kibsgaard, J., & Chorkendorff, I*. (2023). Ultra-high vacuum compatible reactor for model catalyst study of ammonia synthesis at ambient pressure. Review of Scientific Instruments, 94(11). 4. Wei, C., Wang, Z., Otani, K., Hochfilzer, D., Zhang, K., Nielsen, R., et al., Kibsgaard, J*. (2023). Benchmarking Electrocatalyst Stability for Acidic Oxygen Evolution Reaction: The Crucial Role of Dissolved Ion Concentration. ACS Catalysis, 13(21), 14058-14069. 5. Zheng, Y. R.#, Vernieres, J. #, Wang, Z. #, Zhang, K.#, Hochfilzer, D., Krempl, K., et al., Chorkendorff, I*. (2022). Monitoring oxygen production on mass-selected iridium–tantalum oxide electrocatalysts. Nature Energy, 7(1), 55-64. 6. Kaiser, S., Maleki, F., Zhang, K., Harbich, W., Heiz, U., Tosoni, S., et al., Esch, F*. (2021). Cluster catalysis with lattice oxygen: Tracing oxygen transport from a magnetite (001) support onto small Pt clusters. Acs Catalysis, 11(15), 9519-9529. 7. Zhang, K.#, Li, L.#, Goniakowski, J., Noguera, C., Freund, H. J., & Shaikhutdinov, S.* (2021). Size effect in two-dimensional oxide-on-metal catalysts of CO oxidation and its connection to oxygen bonding: An experimental and theoretical approach. Journal of Catalysis, 393, 100-106. 8. Zhang, K.#, Li, L. #, Shaikhutdinov, S.*, & Freund, H. J. (2018). Carbon Monoxide Oxidation on Metal‐Supported Monolayer Oxide Films: Establishing Which Interface is Active. Angewandte Chemie, 130(5), 1275-1279. 9. Weng, X.#, Zhang, K.#, Pan, Q., Martynova, Y., Shaikhutdinov, S.*, & Freund, H. J. (2017). Support Effects on CO Oxidation on Metal‐supported Ultrathin FeO (1 1 1) Films. ChemCatChem, 9(4), 705-712. 10. Zhang, K., Shaikhutdinov, S.*, & Freund, H. J. (2015). Does the surface structure of oxide affect the strong metal–support interaction with platinum? Platinum on Fe3O4 (001) versus Fe3O4 (11 1). ChemCatChem, 7(22), 3725-3730. 11. Davis, E. M., Zhang, K., Cui, Y., Kuhlenbeck, H., Shaikhutdinov, S.*, & Freund, H. J. (2015). Growth of Fe3O4 (001) thin films on Pt (100): Tuning surface termination with an Fe buffer layer. Surface Science, 636, 42-46. 12. Zhang, K., Lin, J., & Wang, Y.* (2015). Phase-selective fluorescence of doped Ge2Sb2Te5 phase-change memory thin films. Chinese Optics Letters, 13(12), 121601. 13. Zhang, K., Li, S., Liang, G., Huang, H., Wang, Y., Lai, T., & Wu, Y.* (2012). Different crystallization processes of as-deposited amorphous Ge2Sb2Te5 films on nano-and picosecond single laser pulse irradiation. Physica B: Condensed Matter, 407(13), 2447-2450. 14. Zhang, K., Zhou, S.*, Zhuang, Y., Yang, R., & Qiu, J. (2012). Bandwidth broadening of near-infrared emission through nanocrystallization in Bi/Ni co-doped glass. Optics Express, 20(8), 8675-8680. 15. Yang, R., Mao, M., Zhang, Y., Zhuang, Y., Zhang, K., & Qiu, J.* (2011). Broadband near-infrared emission from Bi–Er–Tm Co-doped germanate glasses. Journal of non-crystalline solids, 357(11-13), 2396-2399. 16. Liang, G., Zhang, K., Zhai, F., Huang, H., Wang, Y.*, & Wu, Y. (2011). Comparison of optical and electrical transient response during nanosecond laser pulse-induced phase transition of Ge2Sb2Te5 thin films. Chemical Physics Letters, 507(1-3), 203-207 |