曹克诚

EBME Group

课题组长丨研究介绍丨发表论文丨课题组活动丨课题组成员

Group Leader

曹克诚，助理教授、研究员丨Kecheng Cao, Tenure-Track Assistant Professor

通讯地址 Office：物质学院4号楼106室/SPST 4-106

Email：caokch@shanghaitech.edu.cn

个人简历：

2008.09-2012.06 四川大学化学学院本科丨Sichuan university, BE

2012.09-2015.06 四川大学化学学院硕士丨Sichuan university, MSc

2015.10-2019.04 德国乌尔姆大学博士丨Ulm university, PhD

2019.04-2020.11 德国乌尔姆大学博士后丨Ulm university, Postdoc

2020.11-至今上海科技大学助理教授，研究员 | Assistant Professor/PI, ShanghaiTech University

Research

电子束分子工程课题组主要从事基于像差校正透射电子显微镜的电子束辐射化学研究，旨在利用电子束作为成像和分析工具的同时，发展电子束辐照为物质改性和制造的方法。

课题组长期诚聘博士后、硕博连读研究生；欢迎具有物理、化学、材料等相关专业背景,对像差校正透射电子显微镜、辐射化学、电子束分子工程等方向感兴趣的学生学者加盟！

Publications

As Independent PI:

8.Valeria Milotti, Claudia Berkmann, Jorge Laranjeira, Weili Cui, Kecheng Cao, Yifan Zhang, Ute Kaiser, Kazuhiro Yanagi, Manuel Melle-Franco, Lei Shi, Thomas Pichler, and Paola Ayala,Unravelling the Complete Raman Response of Graphene Nanoribbons Discerning the Signature of Edge Passivation.Small Methods,doi: 10.1002/smtd.202200110

7.Hao, J., Zhuang, Z., Cao, K. et al. Unraveling the electronegativity-dominated intermediate adsorption on high-entropy alloy electrocatalysts. Nat Commun 13, 2662 (2022). doi.org/10.1038/s41467-022-30379-4

6.Jican Hao, Zechao Zhuang,Jiace Hao, Kecheng Cao, Yuxiong Hu, Wenbo Wu, Shuanglong Lu,Chan Wang, Nan Zhang, Dingsheng Wang, Mingliang Du, and Han Zhu，“Strain Relaxation in Metal Alloy Catalysts Steers the Product Selectivity of Electrocatalytic CO₂Reduction”,ACS Nano,doi.org/10.1021/acsnano.1c11145

5.Yifan Zhang, Kecheng Cao, Takeshi Saito, Hiromichi Kataura, Hans Kuzmany, Thomas Pichler, Ute Kaiser, Guowei Yang, Lei Shi,“Carbon nanotube-dependent synthesis of armchair graphene nanoribbons”,Nano Research,doi.org/10.1007/s12274-021-3819-8

4.Ma, Y., Ma, Y.-J., Diemant, T., Cao, K.-C., Liu, X., Kaiser, U., Behm, R. J., Varzi, A., Passerini, S., “Unveiling the Intricate Intercalation Mechanism in Manganese Sesquioxide as Positive Electrode in Aqueous Zn-Metal Battery”, Adv. Energy Mater,2021, 11, 2100962. doi.org/10.1002/aenm.202100962

3.Hans Kuzmany, Lei Shi, Miles Martinati, Sofie Cambré, Wim Wenseleers, Jenő Kürti, János Koltai, Gergő Kukucska, Kecheng Cao, Ute Kaiser, Takeshi Saito, Thomas Pichler,“Well-defined sub-nanometer graphene ribbons synthesized inside carbon nanotubes”,Carbon,doi.org/10.1016/j.carbon.2020.08.065

2.Weili Cui, Lei Shi*, Kecheng Cao, Ute Kaiser, Takeshi Saito, Paola Ayala, Thomas Picher*, “Isotopic labelling of confined carbyne”, Angewandte Chemie International Edition, doi.org/10.1002/anie.202017356

1.Yuan Ma, Yanjiao Ma, Thomas Diemant, Kecheng Cao, Ute Kaiser, R. Juergen Behm, Alberto Varzi, Stefano Passerini*, “Embedding Heterostructured α‐MnS/MnO Nanoparticles in S‐doped Carbonaceous Porous Framework as High‐Performance Anode for Lithium‐Ion Batteries”, ChemElectroChem, doi.org/10.1002/celc.202100110

Before independent:

25. Kecheng Cao^#,Stephen T. Skowron^#,Craig T. Stoppiello, Johannes Biskupek, Andrei N. Khlobystov,* and Ute Kaiser*, “Direct imaging of atomic permeation through a vacancy defect in the carbon lattice”,Angewandte Chemie International Edition, 2020, 132, 1–7. (Hot paper, inside cover)

24. Kecheng Cao, Johannes Biskupek, Craig T. Stoppiello, Robert L. McSweeney, Thomas W. Chamberlain, Zheng Liu, Kazu Suenaga, Andrei N. Khlobystov*, Ute Kaiser*, “Atomic mechanism of metal crystal nucleus formation in a single-walled carbon nanotube”, Nature Chemistry, 2020, 12, 921–928.

---Higlighted as News & Views: J. J. De Yoreo & B. A. Legg, “What atoms do when they get together”,Nature Chemistry, 12, 883–885, 2020al crystal nucleus formation”, Nature Chemistry, 2020, 12, 921–928.

23. Kecheng Cao, Stephen T Skowron, Johannes Biskupek, Craig T. Stoppiello, Christopher Leist, Elena Besley, Andrei N. Khlobystov*, Ute Kaiser*, “Imaging an unsupported metal–metal bond in dirhenium molecules at the atomic scale”, Science Advances, 2020, 6, 5849.

---Higlighted by ScienceNews: Emily Conover, ‘A dance of two atoms reveals chemical bonds forming and breaking’.

22. Kecheng Cao, Thilo Zoberbier, Johannes Biskupek, Akos Botos, Robert L McSweeney, Abdullah Kurtoglu, Craig T Stoppiello, Alexander V Markevich, Elena Besley, Thomas W Chamberlain*, Ute Kaiser*, Andrei N Khlobystov*, “Comparison of atomic scale dynamics for the middle and late transition metal nanocatalysts”, Nature Communications,2018,9, 3382.

21. Kecheng Cao, Thomas W Chamberlain, Johannes Biskupek, Thilo Zoberbier, Ute Kaiser*, Andrei N Khlobystov*, “Direct correlation of carbon nanotube nucleation and growth with the atomic structure of re nanocatalysts stimulated and imaged by the electron beam”, Nano Letters, 2018, 18, 6334–6339.

20. Kecheng Cao, Yin Tian, Yongzhi Zhang, Xiaodan Yang, Chiyao Bai, Yue Luo, Xiaosheng Zhao, Lijian Ma*, Shoujian Li*, “Strategy and mechanism for controlling the direction of defect evolution in graphene: preparation of high quality defect healed and hierarchically porous graphene”, Nanoscale, 2014, 6, 13518-13526.

19. Rongji Liu*, Kecheng Cao, Adam H Clark, Peilong Lu, Montaha Anjass, Johannes Biskupek, Ute Kaiser, Guangjin Zhang*, Carsten Streb*, “Top-down synthesis of polyoxometalate-like sub-nanometer molybdenum-oxo clusters as high-performance electrocatalysts”, Chemical Science, 2020,11, 1043-1051

18. Xinghua Guo, Yang Li, Meicheng Zhang, Kecheng Cao, Yin Tian, Yue Qi, Shoujian Li, Kun Li, Xiaoqi Yu, Lijian Ma*.“Colyliform crystalline 2D covalent organic frameworks (COFs) with quasi‐3D topologies for rapid I₂ adsorption”, Angewandte Chemie International Edition, 2020,132, 2 – 11

17. Bugga Balakrishna, Arjun Menon, Kecheng Cao, Sebastian Gsänger, Sebastian B. Beil, Julia Villalva, Oleksandr Shyshov, Oliver Martin, Andreas Hirsch, Bernd Meyer, Ute Kaiser, Dirk M. Guldi, and Max von Delius*, “Dynamic covalent formation of concave disulfide macrocycles mechanically interlocked with single-walled carbon nanotubes”,Angewandte Chemie International Edition, 2020,59, 18774-18785.

16. Hans Kuzmany*, Lei Shi*, Miles Martinati, Sofie Cambré, Wim Wenseleers, Jenő Kürti, János Koltai, Gergő Kukucska, Kecheng Cao, Ute Kaiser, Takeshi Saito, Thomas Pichler, “Well-defined sub-nanometer graphene ribbons synthesized inside carbon nanotubes”, Carbon, 2021, 171, 221-229.

15. Xiaolin Xing, Rongji Liu*, Montaha Anjass, Kecheng Cao, Ute Kaiser, Guangjin Zhang, Carsten Streb*, “Bimetallic manganese-vanadium functionalized N, S-doped carbon nanotubes as efficient oxygen evolution and oxygen reduction electrocatalysts”Applied Catalysis B: Environmental, 2020, 277, 119195

14. Yuan Hu, Kecheng Cao, Lijie Ci, Boris Mizaikoff*, “Selective Chemical Enhancement via Graphene Oxide in Infrared Attenuated Total Reflection Spectroscopy”, The Journal of Physical Chemistry C, 2019, 123, 41, 25286-25293.

13. Xiaolin Xing, Rongji Liu*, Kecheng Cao, Ute Kaiser, Carsten Streb*, “Transition‐metal oxides/carbides@ carbon nanotube composites as multifunctional electrocatalysts for challenging oxidations and reductions”,Chemistry–A European Journal, 2019, 25, 11098-11104.

12. Yuanchun Ji, Yuan Ma, Rongji Liu, Yanjiao Ma, Kecheng Cao, Ute Kaiser, Alberto Varzi, Yu-Fei Song, Stefano Passerini, Carsten Streb,“Modular development of metal oxide/carbon composites for electrochemical energy conversion and storage”, Journal of Materials Chemistry A, 2019, 7, 13096-13102.

11. Yuan Hu, Qiong Chen, Lijie Ci, Kecheng Cao, Boris Mizaikoff,* “Carbon nanodots based attenuated total reflection surface-enhanced infrared absorption spectroscopy and its application to analysis of adenine in aqueous solution” Analytical and bioanalytical chemistry, 2019, 411 (9), 1863–1871.

10. Lei Shi, Kazuhiro Yanagi, Kecheng Cao, Ute Kaiser, Paola Ayala, Thomas Pichler*, “Extraction of linear carbon chains unravels the role of the carbon nanotube host”, ACS nano, 2018, 12, 8477–8484.

9. Xiaolin Xing, Rongji Liu*, Kecheng Cao, Ute Kaiser, Guangjin Zhang, Carsten Streb*, “Manganese vanadium oxide–n-doped reduced graphene oxide composites as oxygen reduction and oxygen evolution electrocatalysts”, ACS applied materials & interfaces, 2018, 10, 51, 44511-44517.

8.Lei Shi*, Jinquan Wei, Kazuhiro Yanagi, Takeshi Saito, Kecheng Cao, Ute Kaiser, Paola Ayala, Thomas Pichler, “Templated direct growth of ultra-thin double-walled carbon nanotubes”, Nanoscale, 2018, 10, 21254-21261.

7. Lei Wang, Xinghua Guo, Kecheng Cao, Bo Li, Yang Li, Meicheng Zhang, Rui Wen, Xing Li, Shoujian Li*, Lijian Ma*,“Effective charge-discriminated group separation of metal ions under highly acidic conditions using nanodiamond-pillared graphene oxide membrane”, Journal of Materials Chemistry A, 2017, 5, 8051-8061.

6, Yin Tian, Jia Fu, Yi Zhang, Bo Li, Chiyao Bai, Kecheng Cao, Shuang Zhang, Xiaosheng Zhao, Yang Li, Lei Wang, Yue Luo, Dongqi Wang*, Shoujian Li*, Lijian Ma*, Ying Xue*, “Insight into the influence of ligand conformation on extraction behaviour of uranium: a combined theoretical and experimental study”, Journal of Nanoscience and Nanotechnology, 2016, 16, 9603-9611.

5,Yin Tian, Jia Fu, Yi Zhang, Kecheng Cao, Chiyao Bai, Dongqi Wang, Shoujian Li*, Ying Xue*, Lijian Ma*, Chong Zheng*, “Ligand-exchange mechanism: new insight into solid-phase extraction of uranium based on a combined experimental and theoretical study”, Physical Chemistry Chemical Physics, 2015, 17, 7214-7223.

4, Chiyao Bai, Juan Li, Songbai Liu, Xiaoyu Yang, Xiaodan Yang, Yin Tian, Kecheng Cao, Ying Huang, Lijian Ma*, Shoujian Li*, “In situ preparation of nitrogen-rich and functional ultramicroporous carbonaceous COFs by “segregated” microwave irradiation”, Microporous and Mesoporous Materials, 2014, 197, 148-155.

3, Xiaodan Yang, Juan Li, Jun Liu, Yin Tian, Bo Li, Kecheng Cao, Songbai Liu, Min Hou, Shoujian Li*, Lijian Ma*, “Simple small molecule carbon source strategy for synthesis of functional hydrothermal carbon: preparation of highly efficient uranium selective solid phase extractant”, Journal of Materials Chemistry A, 2014, 2, 1550-1559.

2, Ying Huang, Chiyao Bai, Kecheng Cao, Yin Tian, Yue Luo, Chuanqin Xia, Songdong Ding, Yongdong Jin, Lijian Ma*, Shoujian Li*, “Chaos to order: an eco-friendly way to synthesize graphene quantum dots”, RSC Advances, 2014, 4, 43160-43165

1, Hang Wang, Lijian Ma, Kehcneg Cao, Junxia Geng, Jun Liu, Qiang Song, Xiaodan Yang, Shoujian Li*, Selective solid-phase extraction of uranium by salicylideneimine-functionalized hydrothermal carbon, Journal of Hazardous Materials, 2012, 229, 321-330

Group activity