杨帆

杨帆课题组介绍

杨帆，副教授/研究员
通讯地址：4号楼112
电子邮件：fyang@shanghaitech.edu.cn
2001年于北京大学化学系获学士学位；2007年于美国得克萨斯A&M大学化学系获博士学位；2008-2012年先后于美国得克萨斯A&M大学、美国布鲁克海文国家实验室从事博士后研究；自2012年8月，在中国科学院大连化学物理研究所催化基础国家重点实验室包信和院士团队工作，任研究员/博士生导师。2019年12月，加入上海科技大学物质科学与技术学院，兼任分析测试中心主任。

研究介绍

杨帆研究员主要从事纳米结构的表界面催化研究，近期研究主要涉及金属-氧化物界面和负载团簇结构在热催化与电催化过程中的作用，通过开发基于扫描探针与红外的原位动态表征方法，获得纳米结构表界面催化反应的原子/分子尺度理解。近5年来在Nat. Commun.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、ACS Catal.、Energy Environ. Sci.等国际知名刊物上发表SCI 论文50余篇。主持或参与承担自然科学基金委面上/重点/集成项目，科技部国家重点研发计划，中科院先导项目，中科院-美国能源部交流合作项目等基础科研项目。

本课题组长期诚聘副研究员、助理研究员、博士后、硕博连读研究生，待遇优厚，工作环境优越，欢迎有志于在催化化学、表面科学等领域开展最前沿研究的学生学者加入！有意者请直接与杨帆邮件联系。

发表文章

1. Zhu, B.; Huang, W.; Lin, H.; Feng, H.; Palotás, K.; Lv, J.; Ren, Y.; Ouyang, R.*; Yang, F.*, Vacancy ordering in ultrathin copper oxide films on Cu(111). J. Am. Chem. Soc.2024,146 (23), 15887-15896.

2. Shao, W.; Zhang, Y.; Zhou, Z.; Li, N.; Jiao, F.; Ling, Y.; Li, Y.; Zhou, Z.; Cao, Y.; Liu, Z.; Pan, X.; Fu, Q.; Wöll, C.; Liu, P.; Bao, X.; Yang, F.*, Dynamic control and quantification of active sites on ceria for CO activation and hydrogenation. Nat. Commun.2024,15 (1), 9620.

3. Deng, X.; Zheng, C.; Li, Y.; Zhou, Z.; Wang, J.; Ran, Y.; Hu, Z.*; Yang, F.*; Li, L.*, Conductive catalysis by subsurface transition metals. Nat. Sci. Rev.2024,11 (1), nwae015.

4. Zhou, Q.; Zhou, Z.; Lu, S.; Wang, L.; Zhan, X.; Peng, H.; Cai, J.; Wang, B.; Han, Y.; Zhao, A.; Tang, S.; Yang, F.*; Liu, Z.*, Increasing reactivity of ceria through water assisted surface modification. Appl. Surf. Sci.2024,656, 159666.

5. Zhang, H.; Zhang, H.; Wang, R.; Lv, J.; Huang, W.; Guo, C.; Yang, F.*, Enhancing oxygen evolution reaction with two-dimensional nickel oxide on Au (111). Catalysts2024,14 (5), 284.

6. Li, J.; Zhang, L.; Ma, Y.; Fan, K.; Zhang, J.; Wu, J.; Yan, W.; Meng, X.*; Wu, Q.; Yang, F.*; Xiao, F.-S.*, Selective catalytic reduction of NO_x with methane over cobalt-exchanged SSZ-39 zeolite. Chem. Eng. J.2024,496, 153191.

7. Wang, Y.-Q.; Fu, J.; Feng, Y.; Zhao, K.; Wang, L.; Cai, J.-Y.; Wang, X.; Chen, T.; Yang, F.; Hu, J.-S.; Xu, B.; Wang, D.*; Wan, L.-J.*, Alkali metal cations induce structural evolution on Au(111) during cathodic polarization. J. Am. Chem. Soc.2024,146 (40), 27713-27724.

8. Wang, M.; Zheng, L.; Wang, G.; Cui, J.; Guan, G.-L.; Miao, Y.-T.; Wu, J.-F.; Gao, P.; Yang, F.; Ling, Y.; Luo, X.; Zhang, Q.; Fu, G.; Cheng, K.; Wang, Y.*, Spinel nanostructures for the hydrogenation of CO₂ to methanol and hydrocarbon chemicals. J. Am. Chem. Soc.2024,146 (21), 14528-14538.

9. Yang, C.; Ma, S.; Liu, Y.; Wang, L.; Yuan, D.; Shao, W.-P.; Zhang, L.; Yang, F.; Lin, T.; Ding, H.; He, H.; Liu, Z.-P.; Cao, Y.; Zhu, Y.*; Bao, X.*, Homolytic H₂dissociation for enhanced hydrogenation catalysis on oxides. Nat. Commun.2024,15 (1), 540.

10. Li, X.; Xu, Z.; Bu, D.; Cai, J.; Chen, H.; Chen, Q.; Chen, T.; Cheng, F.; Chi, L.; Dong, W.; Dong, Z.; Du, S.; Fan, Q.; Fan, X.; Fu, Q.; Gao, S.; Guo, J.; Guo, W.; He, Y.; Hou, S.; Jiang, Y.; Kong, H.; Li, B.; Li, D.; Li, J.; Li, Q.; Li, R.; Li, S.; Lin, Y.; Liu, M.; Liu, P.; Liu, Y.; Lü, J.; Ma, C.; Pan, H.; Pan, J.; Pan, M.; Qiu, X.; Shen, Z.; Tan, S.; Wang, B.; Wang, D.; Wang, L.; Wang, L.; Wang, T.; Wang, X.; Wang, X.; Wang, X.; Wang, Y.; Wang, Y.; Wu, K.; Xu, W.; Xue, N.; Yan, L.; Yang, F.; Yang, Z.; Zhang, C.; Zhang, X.; Zhang, Y.; Zhang, Y.; Zhou, X.; Zhu, J.; Zhang, Y.; Gao, F.*; Wang, Y.*, Recent progress on surface chemistry II: Property and characterization. Chin. Chem. Lett.2024,36 (1), 110100.

11. Li, X.; Xu, Z.; Bu, D.; Cai, J.; Chen, H.; Chen, Q.; Chen, T.; Cheng, F.; Chi, L.; Dong, W.; Dong, Z.; Du, S.; Fan, Q.; Fan, X.; Fu, Q.; Gao, S.; Guo, J.; Guo, W.; He, Y.; Hou, S.; Jiang, Y.; Kong, H.; Li, B.; Li, D.; Li, J.; Li, Q.; Li, R.; Li, S.; Lin, Y.; Liu, M.; Liu, P.; Liu, Y.; Lü, J.; Ma, C.; Pan, H.; Pan, J.; Pan, M.; Qiu, X.; Shen, Z.; Tan, S.; Wang, B.; Wang, D.; Wang, L.; Wang, L.; Wang, T.; Wang, X.; Wang, X.; Wang, X.; Wang, Y.; Wang, Y.; Wu, K.; Xu, W.; Xue, N.; Yan, L.; Yang, F.; Yang, Z.; Zhang, C.; Zhang, X.; Zhang, Y.; Zhang, Y.; Zhou, X.; Zhu, J.; Zhang, Y.; Gao, F.*; Wang, Y.*, Recent progress on surface chemistry I: Assembly and reaction. Chin. Chem. Lett.2024,35 (12), 110055.

12. Zhao, S.; Fan, K.; Li, J.; Ma, Y.; Yang, F.; Meng, X.; Xiao, F.-S.*, Hydrophobic modification of zeolite-supported platinum catalysts for complete oxidation of toluene. Catal. Today2024,432, 114601.

13. Lan, Y.; Wang, L.; Luo, Y.; Hao, R.; Zhang, H.; Aruta, C.; Yang, F.; Yu, Y.; Yang, N.*, Engineering lanthanum into Pt doped CeO₂ for Intermediate temperature solid oxide fuel cells. J. Eur. Ceram. Soc.2024,44 (2), 996-1004.

14. Fei, Y.; Yang, W.; Guo, Z.; Sun, H.; Yang, F.; Hu, J.*, Study of cell adhesion, osteogenesis, and angiogenesis of a “groove” structure micro-arc oxidation titanium. Applied Surface Science Advances2024,19, 100552.

15. Ding, B.; Yang, C.; Chen, Y.; Shao, W.-P.; Yang, F.; Zhang, C.; Wang, Z.; Liu, Y.; Cao, Y.; Zhu, Y.*; Bao, X.*, Cr₂O₃ clusters on ZnO as hydrogen pools for efficient syngas‐to‐light olefins. ChemCatChem2024,16 (23), e202401421.

16. Zhang, Y.; Li, H.; Liu, F.; Li, M.; Zhang, Y.; Cai, J.; Li, Y.; Yang, F.; Yin, F.; Lu, J.; Zhang, T.; Yang, B.*, Revealing dynamics and competitive mechanism of gas-induced surface segregation of PdFe0.08 dilute alloy by multi-dimensional imaging. J. Phys. Chem. Lett.2024,15 (47), 11737-11744.

17. Chen, Z.; Wen, J.; Zeng, Y.; Li, M.; Tian, Y.; Yang, F.; Li, M. M.-J.; Chen, P.; Huang, H.; Ye, D.; Chen, L.*, The origin of the mediocre methanol selectivity of Cu/ZnO-based catalysts for methanol synthesis from CO₂ hydrogenation. Appl. Catal. B2024,340, 123192.

18. Ling, Y.; Luo, J.; Ran, Y.; Liu, Z.; Li, W.-X.; Yang, F.*, Atomic-scale visualization of heterolytic H₂ dissociation and CO_x hydrogenation on ZnO under ambient conditions. J. Am. Chem. Soc.2023,145 (41), 22697-22707.

19. Zhou, Z.; Chen, L.; Wang, L.; Liu, Y.; Cheng, P.; Peng, H.; Cai, J.; Zhou, Q.; Wang, Y.; Yang, N.; Wang, B.; Gong, X.-Q.; Yang, F.*; Liu, Z.*, Selective hydrogenation of propyne to propene promoted by synergistic effect of surface oxygen vacancies and hydride species on Ceria. ACS Catal.2023,13 (14), 9588-9596.

20. Wang, X.; Guo, C.; Zhu, B.; Xiao, D.; Gao, D.; Liu, Z.; Yang, F.*, Reaction-induced iodine adsorption on Cu surfaces facilitates electrocatalytic CO₂ reduction. J. Chem. Phys.2023,158 (20), 204701.

21. Zhao, L.; Zhang, L.; Wu, Z.; Huang, C.; Chen, K.; Wang, H.; Yang, F.*, Size effect of Cu particles on interface formation in Cu/ZnO catalysts for methanol synthesis. Catalysts2023,13 (8), 1190.

22. Zhou, Q.; Akber, H.; Zhao, A.; Yang, F.*; Liu, Z.*, Interaction of water with ceria thin film. ChemCatChem2023,15 (15), e2023003.

23. Cai, J.; Ling, Y.; Zhang, H.; Yang, B.; Yang, F.*; Liu, Z.*, Formation of different Rh–O species on Rh(110) and their reaction with CO. ACS Catal.2023,13 (1), 11-18.

24. Zang, Y.; Cai, J.; Han, Y.; Wu, H.; Zhu, W.; Shi, S.; Zhang, H.; Ran, Y.; Yang, F.; Ye, M.; Yang, B.; Li, Y.; Liu, Z.*, CO₂ activation on Ni(111) and Ni(110) surfaces in the presence of hydrogen. J. Phys. Chem. Lett.2023,14 (19), 4381-4387.

25. Li, Z.; Chen, L.; Wu, Z.; Jia, A.; Shi, S.; Zhang, H.; Wang, J.; Liu, Z.; Shao, W.-P.; Yang, F.; Wu, X.-P.; Gong, X.-Q.; Huang, W.*, Surface oxygen vacancy and hydride species on Ceria are detrimental to acetylene semihydrogenation reaction. ACS Catal.2023,13 (8), 5213-5224.

26. Wu, M.-Y.; Wang, B.-B.; Wang, W.-W.; Yang, F.; Jia, C.-J.*, Dynamic structural evolution of CeO₂ in CuO−CeO₂ catalyst revealed by in situ spectroscopy. ChemCatChem2023,15 (22), e202300894.

27. Liu, Q.; Li, Y.; Zhao, X.; Zhu, B.; Yi, Z.; Yang, F.*; Bao, X., Dynamic structural changes of iron oxide nanostructures on Cu(111). J. Phys. Chem. C2022,126 (4), 2041-2048.

28. Liu, K.; Jiang, L.; Huang, W.; Zhu, G.; Zhang, Y.-J.; Xu, C.; Qin, R.; Liu, P.; Hu, C.; Wang, J.; Li, J.-F.; Yang, F.*; Fu, G.*; Zheng, N.*, Atomic overlayer of permeable microporous cuprous oxide on palladium promotes hydrogenation catalysis. Nat. Commun.2022,13 (1), 2597.

29. Ling, Y.; Ran, Y.; Shao, W.; Li, N.; Jiao, F.; Pan, X.; Fu, Q.; Liu, Z.; Yang, F.*; Bao, X., Probing active species for CO hydrogenation over ZnCr₂O₄ catalysts. Chin. J. Catal.2022,43 (8), 2017-2025.

30. Ling, Y.; Luo, J.; Ran, Y.; Cao, Y.; Huang, W.; Cai, J.; Liu, Z.; Li, W.-X.*; Yang, F.*; Bao, X., Dynamic chemical processes on ZnO surfaces tuned by physisorption under ambient conditions. J. Energy Chem.2022,72, 258-264.

31. Su, X.; Jiang, Z.; Zhou, J.; Liu, H.; Zhou, D.; Shang, H.; Ni, X.; Peng, Z.; Yang, F.; Chen, W.; Qi, Z.; Wang, D.; Wang, Y.*, Complementary Operando Spectroscopy identification of in-situ generated metastable charge-asymmetry Cu₂-CuN₃ clusters for CO₂ reduction to ethanol. Nat. Commun.2022,13 (1), 1322.

32. Sang, J.; Wei, P.; Liu, T.; Lv, H.; Ni, X.; Gao, D.; Zhang, J.; Li, H.; Zang, Y.; Yang, F.; Liu, Z.; Wang, G.*; Bao, X.*, A reconstructed Cu₂P₂O₇ catalyst for selective CO₂ electroreduction to multicarbon products. Angew. Chem. Int. Ed.2022,61 (5), e202114238.

33. Xu, W.; Ni, X.; Zhang, L.; Yang, F.; Peng, Z.; Huang, Y.; Liu, Z.*, Tuning the electronic structure of tungsten oxide for enhanced hydrogen evolution reaction in alkaline electrolyte. ChemElectroChem2022,9 (5), e202101300.

34. Mao, Z.; Ding, C.; Liu, X.; Zhang, Q.; Qin, X.; Li, H.; Yang, F.; Li, Q.; Zhang, X.-G.; Zhang, J.; Cai, W.-B.*, Interstitial B-doping in Pt lattice to upgrade oxygen electroreduction performance. ACS Catal.2022,12 (15), 8848-8856.

35. Zhan, X.; Luo, Y.; Wang, Z.; Xiang, Y.; Peng, Z.; Han, Y.; Zhang, H.; Chen, R.; Zhou, Q.; Peng, H.; Huang, H.; Liu, W.; Ou, X.; Ma, G.; Fan, F.; Yang, F.; Li, C.; Liu, Z.*, Formation of multifaceted nano-groove structure on rutile TiO₂ photoanode for efficient electron-hole separation and water splitting. J. Energy Chem.2022,65, 19-25.

36. Li, X.; Zhang, H.; Ran, Y.; Ye, M.; Yang, F.; Han, Y.; Liu, Z.*, Beam-induced effects on platinum oxidation during ambient-pressure X-ray photoelectron spectroscopy. J. Phys. Chem. Lett.2022,13 (24), 5677-5682.

37. Jin, C.; Wang, B.; Zhou, Y.*; Yang, F.*; Han, S.; Guo, P.; Liu, Z.; Shen, W.*, Gold atomic layers and isolated atoms on MoC for the low-temperature water gas shift reaction. ACS Catal.2022,12 (24), 15648-15657.

38. Jin, C.; Wang, B.; Zhou, Y.*; Yang, F.*; Guo, P.; Liu, Z.; Shen, W.*, Restructuring of the gold-carbide interface for low-temperature water-gas shift. Chem. Comm.2022,58 (52), 7313-7316.

39. Huang, W.*; Yang, F.*, Preface to special column on surface & interface chemistry connecting thermo-, photo- and electro-catalysis. Chin. J. Catal.2022,43 (8), 1963.

40. Dong, A.; Lin, L.; Mu, R.; Li, R.; Li, K.; Wang, C.; Cao, Y.; Ling, Y.; Chen, Y.; Yang, F.; Pan, X.; Fu, Q.*; Bao, X.*, Modulating the formation and evolution of surface hydrogen species on ZnO through Cr addition. ACS Catal.2022,12 (10), 6255-6264.

41. Zhou, Q.; Cai, J.; Wang, W.; Liu, Z.*; Yang, F.*, In-situ studies of catalytic reactions over well-defined model catalysts. In Catal., The Royal Society of Chemistry: Cambridge, 2021; Vol. 33, pp 380-416.

42. Zhan, X.; Peng, Z.; Huang, H.; Zhang, H.; Liu, Z.; Ou, X.; Yang, F.*; Liu, Z.*, Photoelectrochemical performance enhancement of low-energy Ar⁺ irradiation modified TiO₂. Appl. Surf. Sci.2021,541, 148527.

43. Yang, J.; Fu, W.; Chen, C.; Chen, W.; Huang, W.; Yang, R.; Kong, Q.; Zhang, B.; Zhao, J.; Chen, C.; Luo, J.; Yang, F.; Duan, X.*; Jiang, Z.*; Qin, Y.*, Atomic design and fine-tuning of subnanometric Pt catalysts to tame hydrogen generation. ACS Catal.2021,11 (7), 4146-4156.

44. Wang, Y.; Zhou, Q.; Kang, L.; Yang, L.; Wu, H.; Zhou, Z.; Xiao, C.; Guo, J.; Yang, F.*; Zhang, S.*; Li, G.; Jin, Y. *, Oxide-water interaction and wetting property of ceria surfaces tuned by high-temperature thermal aging. Appl. Surf. Sci.2021,554, 149658.

45. Wang, Y.; Ren, P.; Hu, J.; Tu, Y.; Gong, Z.; Cui, Y.; Zheng, Y.; Chen, M.; Zhang, W.; Ma, C.; Yu, L.; Yang, F.; Wang, Y.; Bao, X.; Deng, D.*, Electron penetration triggering interface activity of Pt-graphene for CO oxidation at room temperature. Nat. Commun.2021,12 (1), 5814.

46. Wang, B.; Zhang, L.; Cai, J.; Peng, Z.; Cheng, P.; Li, X.; Zhang, H.; Yang, F.*; Liu, Z.*, Formation and activity enhancement of surface hydrides by the metal–oxide interface. Adv. Mater. Int.2021,8 (7), 2002169.

47. Li, Y.; Zhao, X.; Cui, Y.; Yang, F.*; Bao, X., Oxidation-induced structural transition of two-dimensional iron oxide on Au(111). J. Phys. D: Appl. Phys.2021,54 (20), 204003.

48. Huang, W.; Cai, J.; Hu, J.; Zhu, J.; Yang, F.*; Bao, X., Atomic structures and electronic properties of Cr-doped ZnO surfaces. Chin. J. Catal.2021,42 (6), 971-979.

49. Huang, W.; Liu, Q.; Zhou, Z.; Li, Y.; Ling, Y.; Wang, Y.; Tu, Y.; Wang, B.; Zhou, X.; Deng, D.; Yang, B.; Yang, Y.; Liu, Z.; Bao, X.; Yang, F.*, Tuning the activities of cuprous oxide nanostructures via the oxide-metal interaction. Nat. Commun.2020,11 (1), 2312.

50. Zheng, Z.-Y.; Wang, D.; Zhang, Y.; Yang, F.; Gong, X.-Q.*, Structures and reactivities of the CeO₂/Pt(111) reverse catalyst: A DFT+U study. Chin. J. Catal.2020,41 (9), 1360-1368.

51. Wang, B.; Zhang, H.; Xu, W.; Li, X.; Wang, W.; Zhang, L.; Li, Y.; Peng, Z.; Yang, F.*; Liu, Z.*, Nature of active sites on Cu-CeO₂ catalysts activated by high-temperature thermal aging. ACS Catal.2020,10 (21), 12385-12392.

52. Li, Y.; Yang, B.; Xia, M.; Yang, F.*; Bao, X., Oxidation-induced segregation of FeO on the Pd-Fe alloy surface. Appl. Surf. Sci.2020,525, 146484.

53. Li, Y.; Chen, H.; Wang, W.; Huang, W.; Ning, Y.; Liu, Q.; Cui, Y.; Han, Y.; Liu, Z.; Yang, F.*; Bao, X., Crystal-plane-dependent redox reaction on Cu surfaces. Nano Res.2020,13 (6), 1677-1685.

54. Ding, C.; Mao, Z.; Liang, J.-S.; Qin, X.; Zhang, Q.; Yang, F.; Li, Q.; Cai, W.-B.*, Aqueous phase approach to Au-modified Pt–Co/C toward efficient and durable cathode catalyst of PEMFCs. J. Phys. Chem. C2021,125 (43), 23821-23829.

55. Cao, Y.; Luo, J.; Huang, W.; Ling, Y.; Zhu, J.; Li, W.-X.*; Yang, F.*; Bao, X., Probing surface defects of ZnO using formaldehyde. J. Chem. Phys.2020,152 (7), 074714.

56. 贾佳; 陆晴; 杨帆, 基于NMF算法的全球碳中和技术领域研究态势分析. 科学观察 2022, 1-23.

本组成员