杨帆课题组介绍
课题组长 |
研究介绍 |
杨帆研究员主要从事纳米结构的表界面催化研究,近期研究主要涉及金属-氧化物界面和负载团簇结构在热催化与电催化过程中的作用,通过开发基于扫描探针与红外的原位动态表征方法,获得纳米结构表界面催化反应的原子/分子尺度理解。近5年来在Nat. Commun.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、ACS Catal.、Energy Environ. Sci.等国际知名刊物上发表SCI 论文50余篇。主持或参与承担自然科学基金委面上/重点/集成项目,科技部国家重点研发计划,中科院先导项目,中科院-美国能源部交流合作项目等基础科研项目。 本课题组长期诚聘副研究员、助理研究员、博士后、硕博连读研究生,待遇优厚,工作环境优越,欢迎有志于在催化化学、表面科学等领域开展最前沿研究的学生学者加入!有意者请直接与杨帆邮件联系。 |
发表文章 |
1. Ling, Y.; Luo, J.; Ran, Y.; Liu, Z.; Li, W.-X.; Yang, F., Atomic-Scale Visualization of Heterolytic H2 Dissociation and COx Hydrogenation on ZnO under Ambient Conditions. J. Am. Chem. Soc. 2023,145 (41), 22697-22707.
2. Lan, Y.; Wang, L.; Luo, Y.; Hao, R.; Zhang, H.; Aruta, C.; Yang, F.; Yu, Y.; Yang, N., Engineering Lanthanum into Pt doped CeO2 for Intermediate Temperature Solid Oxide Fuel Cells. J. Eur. Ceram. Soc. 2023,44 (2), 996-1004.
3. Zhou, Q.; Zhou, Z.; Lu, S.; Wang, L.; Zhan, X.; Peng, H.; Cai, J.; Wang, B.; Han, Y.; Zhao, A.; Tang, S.; Yang, F.; Liu, Z., Increasing reactivity of ceria through water assisted surface modification. Appl. Surf. Sci. 2024,656, 159666.
4. Deng, X.; Zheng, C.; Li, Y.; Zhou, Z.; Wang, J.; Ran, Y.; Hu, Z.; Yang, F.; Li, L., Conductive catalysis by subsurface transition metals. Nat. Sci. Rev. 2024,11 (1), nwae015.
5. Zhou, Z.; Chen, L.; Wang, L.; Liu, Y.; Cheng, P.; Peng, H.; Cai, J.; Zhou, Q.; Wang, Y.; Yang, N.; Wang, B.; Gong, X.-Q.; Yang, F.; Liu, Z., Selective Hydrogenation of Propyne to Propene Promoted by Synergistic Effect of Surface Oxygen Vacancies and Hydride Species on Ceria. ACS Catal. 2023,13 (14), 9588-9596.
6. Zhou, Q.; Akber, H.; Zhao, A.; Yang, F.; Liu, Z., Interaction of water with ceria thin film. ChemCatChem 2023,15 (15), e2023003.
7. Zhao, L.; Zhang, L.; Wu, Z.; Huang, C.; Chen, K.; Wang, H.; Yang, F., Size Effect of Cu Particles on Interface Formation in Cu/ZnO Catalysts for Methanol Synthesis. Catalysts 2023,13 (8), 1190.
8. Zang, Y.; Cai, J.; Han, Y.; Wu, H.; Zhu, W.; Shi, S.; Zhang, H.; Ran, Y.; Yang, F.; Ye, M.; Yang, B.; Li, Y.; Liu, Z., CO2 Activation on Ni(111) and Ni(110) Surfaces in the Presence of Hydrogen. J. Phys. Chem. Lett. 2023, 4381-4387.
9. Wu, M.-Y.; Wang, B.-B.; Wang, W.-W.; Yang, F.; Jia, C.-J., Dynamic Structural Evolution of CeO2 in CuO−CeO2 Catalyst Revealed by In Situ Spectroscopy. ChemCatChem 2023,15 (22), e202300894.
10. Wang, X.; Guo, C.; Zhu, B.; Xiao, D.; Gao, D.; Liu, Z.; Yang, F., Reaction-induced iodine adsorption on Cu surfaces facilitates electrocatalytic CO2 reduction. J. Chem. Phys. 2023,158 (20), 204701.
11. Li, Z.; Chen, L.; Wu, Z.; Jia, A.; Shi, S.; Zhang, H.; Wang, J.; Liu, Z.; Shao, W.-P.; Yang, F.; Wu, X.-P.; Gong, X.-Q.; Huang, W., Surface Oxygen Vacancy and Hydride Species on Ceria Are Detrimental to Acetylene Semihydrogenation Reaction. ACS Catal. 2023,13, 5213-5224.
12. Chen, Z.; Wen, J.; Zeng, Y.; Li, M.; Tian, Y.; Yang, F.; Li, M. M.-J.; Chen, P.; Huang, H.; Ye, D.; Chen, L., The origin of the mediocre methanol selectivity of Cu/ZnO-based catalysts for methanol synthesis from CO2 hydrogenation. Appl. Catal. B 2024,340, 123192.
13. Cai, J.; Ling, Y.; Zhang, H.; Yang, B.; Yang, F.; Liu, Z., Formation of Different Rh–O Species on Rh(110) and Their Reaction with CO. ACS Catal. 2023,13 (1), 11-18.
14. 贾佳; 陆晴; 杨帆, 基于NMF算法的全球碳中和技术领域研究态势分析. 科学观察 2022, 1-23.
15. Xu, W.; Ni, X.; Zhang, L.; Yang, F.; Peng, Z.; Huang, Y.; Liu, Z., Tuning the electronic structure of tungsten oxide for enhanced hydrogen evolution reaction in alkaline electrolyte. ChemElectroChem 2022,9 (5), e202101300.
16. Su, X.; Jiang, Z.; Zhou, J.; Liu, H.; Zhou, D.; Shang, H.; Ni, X.; Peng, Z.; Yang, F.; Chen, W.; Qi, Z.; Wang, D.; Wang, Y., Complementary Operando Spectroscopy identification of in-situ generated metastable charge-asymmetry Cu2-CuN3 clusters for CO2 reduction to ethanol. Nat. Commun. 2022,13 (1), 1322.
17. Sang, J.; Wei, P.; Liu, T.; Lv, H.; Ni, X.; Gao, D.; Zhang, J.; Li, H.; Zang, y.; Yang, F.; Liu, Z.; Wang, G.; Bao, X., A reconstructed Cu2P2O7 catalyst for selective CO2 electroreduction to multicarbon products. Angew. Chem. Int. Ed. 2022,61 (5), e202114238.
18. Mao, Z.; Ding, C.; Liu, X.; Zhang, Q.; Qin, X.; Li, H.; Yang, F.; Li, Q.; Zhang, X.-G.; Zhang, J.; Cai, W.-B., Interstitial B-Doping in Pt Lattice to Upgrade Oxygen Electroreduction Performance. ACS Catal. 2022, 8848-8856.
19. Liu, Q.; Li, Y.; Zhao, X.; Zhu, B.; Yi, Z.; Yang, F.; Bao, X., Dynamic structural changes of iron oxide nanostructures on Cu(111). J. Phys. Chem. C 2022,126 (4), 2041-2048.
20. Liu, K.; Jiang, L.; Huang, W.; Zhu, G.; Zhang, Y.-J.; Xu, C.; Qin, R.; Liu, P.; Hu, C.; Wang, J.; Li, J.-F.; Yang, F.; Fu, G.; Zheng, N., Atomic overlayer of permeable microporous cuprous oxide on palladium promotes hydrogenation catalysis. Nat. Commun. 2022,13 (1), 2597.
21. Ling, Y.; Ran, Y.; Shao, W.; Li, N.; Jiao, F.; Pan, X.; Fu, Q.; Liu, Z.; Yang, F.; Bao, X., Probing active species for CO hydrogenation over ZnCr2O4 catalysts. Chin. J. Catal. 2022,43 (8), 2017-2025.
22. Ling, Y.; Luo, J.; Ran, Y.; Cao, Y.; Huang, W.; Cai, J.; Liu, Z.; Li, W.-X.; Yang, F.; Bao, X., Dynamic chemical processes on ZnO surfaces tuned by physisorption under ambient conditions. J. Energy Chem. 2022,72, 258-264.
23. Li, X.; Zhang, H.; Ran, Y.; Ye, M.; Yang, F.; Han, Y.; Liu, Z., Beam-Induced Effects on Platinum Oxidation during Ambient-Pressure X-ray Photoelectron Spectroscopy. J. Phys. Chem. Lett. 2022, 5677-5682.
24. Jin, C.; Wang, B.; Zhou, Y.; Yang, F.; Han, S.; Guo, P.; Liu, Z.; Shen, W., Gold Atomic Layers and Isolated Atoms on MoC for the Low-Temperature Water Gas Shift Reaction. ACS Catal. 2022,12 (24), 15648-15657.
25. Jin, C.; Wang, B.; Zhou, Y.; Yang, F.; Guo, P.; Liu, Z.; Shen, W., Restructuring of the gold-carbide interface for low-temperature water-gas shift. Chem. Comm. 2022,58 (52), 7313-7316.
26. Huang, W.; Yang, F., Preface to special column on surface & interface chemistry connecting thermo-, photo- and electro-catalysis. Chin. J. Catal. 2022,43 (8), 1963.
27. Dong, A.; Lin, L.; Mu, R.; Li, R.; Li, K.; Wang, C.; Cao, Y.; Ling, Y.; Chen, Y.; Yang, F.; Pan, X.; Fu, Q.; Bao, X., Modulating the Formation and Evolution of Surface Hydrogen Species on ZnO through Cr Addition. ACS Catal. 2022, 6255-6264.
28. Zhou, Q.; Cai, J.; Wang, W.; Liu, Z.; Yang, F., In-situ studies of catalytic reactions over well-defined model catalysts. In Catal., The Royal Society of Chemistry: 2021; Vol. 33, pp 380-416.
29. Zhan, X.; Peng, Z.; Huang, H.; Zhang, H.; Liu, Z.; Ou, X.; Yang, F.; Liu, Z., Photoelectrochemical performance enhancement of low-energy Ar+ irradiation modified TiO2. Appl. Surf. Sci. 2021,541, 148527.
30. Zhan, X.; Luo, Y.; Wang, Z.; Xiang, Y.; Peng, Z.; Han, Y.; Zhang, H.; Chen, R.; Zhou, Q.; Peng, H.; Huang, H.; Liu, W.; Ou, X.; Ma, G.; Fan, F.; Yang, F.; Li, C.; Liu, Z., Formation of multifaceted nano-groove structure on rutile TiO2 photoanode for efficient electron-hole separation and water splitting. J. Energy Chem. 2021,65, 19-25.
31. Yang, J.; Fu, W.; Chen, C.; Chen, W.; Huang, W.; Yang, R.; Kong, Q.; Zhang, B.; Zhao, J.; Chen, C.; Luo, J.; Yang, F.; Duan, X.; Jiang, Z.; Qin, Y., Atomic design and fine-tuning of subnanometric Pt catalysts to tame hydrogen generation. ACS Catal. 2021,11 (7), 4146-4156.
32. Wang, Y.; Zhou, Q.; Kang, L.; Yang, L.; Wu, H.; Zhou, Z.; Xiao, C.; Guo, J.; Yang, F.; Zhang, S.; Li, G.; Jin, Y., Oxide-water interaction and wetting property of ceria surfaces tuned by high-temperature thermal aging. Appl. Surf. Sci. 2021,554, 149658.
33. Wang, Y.; Ren, P.; Hu, J.; Tu, Y.; Gong, Z.; Cui, Y.; Zheng, Y.; Chen, M.; Zhang, W.; Ma, C.; Yu, L.; Yang, F.; Wang, Y.; Bao, X.; Deng, D., Electron penetration triggering interface activity of Pt-graphene for CO oxidation at room temperature. Nat. Commun. 2021,12 (1), 5814.
34. Wang, B.; Zhang, L.; Cai, J.; Peng, Z.; Cheng, P.; Li, X.; Zhang, H.; Yang, F.; Liu, Z., Formation and activity enhancement of surface hydrides by the metal–oxide interface. Adv. Mater. Int. 2021,8 (7), 2002169.
35. Li, Y.; Zhao, X.; Cui, Y.; Yang, F.; Bao, X., Oxidation-induced structural transition of two-dimensional iron oxide on Au(111). J. Phys. D: Appl. Phys. 2021,54 (20), 204003.
36. Huang, W.; Cai, J.; Hu, J.; Zhu, J.; Yang, F.; Bao, X., Atomic structures and electronic properties of Cr-doped ZnO surfaces. Chin. J. Catal. 2021,42 (6), 971-979.
37. Ding, C.; Mao, Z.; Liang, J.-S.; Qin, X.; Zhang, Q.; Yang, F.; Li, Q.; Cai, W.-B., Aqueous phase approach to Au-modified Pt–Co/C toward efficient and durable cathode catalyst of PEMFCs. J. Phys. Chem. C 2021,125 (43), 23821-23829.
38. Zheng, Z.-Y.; Wang, D.; Zhang, Y.; Yang, F.; Gong, X.-Q., Structures and reactivities of the CeO2/Pt(111) reverse catalyst: A DFT+U study. Chin. J. Catal. 2020,41 (9), 1360-1368.
39. Wang, B.; Zhang, H.; Xu, W.; Li, X.; Wang, W.; Zhang, L.; Li, Y.; Peng, Z.; Yang, F.; Liu, Z., Nature of active sites on Cu-CeO2 catalysts activated by high-temperature thermal aging. ACS Catal. 2020,10 (21), 12385-12392.
40. Li, Y.; Yang, B.; Xia, M.; Yang, F.; Bao, X., Oxidation-induced segregation of FeO on the Pd-Fe alloy. Appl. Surf. Sci. 2020,525, 146484.
41. Li, Y.; Chen, H.; Wang, W.; Huang, W.; Ning, Y.; Liu, Q.; Cui, Y.; Han, Y.; Liu, Z.; Yang, F.; Bao, X., Crystal-plane-dependent redox reaction on Cu surfaces. Nano Res. 2020,13 (6), 1677-1685.
42. Huang, W.; Liu, Q.; Zhou, Z.; Li, Y.; Ling, Y.; Wang, Y.; Tu, Y.; Wang, B.; Zhou, X.; Deng, D.; Yang, B.; Yang, Y.; Liu, Z.; Bao, X.; Yang, F., Tuning the activities of cuprous oxide nanostructures via the oxide-metal interaction. Nat. Commun. 2020,11 (1), 2312.
43. Cao, Y.; Luo, J.; Huang, W.; Ling, Y.; Zhu, J.; Li, W.-X.; Yang, F.; Bao, X., Probing surface defects of ZnO using formaldehyde. J. Chem. Phys. 2020,152 (7), 074714.
44. Zhou, Z.; Liu, P.; Yang, F.; Bao, X., Interface-confined triangular FeOx nanoclusters on Pt(111). J. Chem. Phys. 2019,151 (21), 214704.
45. Zhang, Y.; Yang, F.; Bao, X., Growth and structures of monolayer and bilayer CeOx nanostructures on Au(111). Surf. Sci. 2019,679, 31-36.
46. Zhang, Y.; Feng, W.; Yang, F.; Bao, X., Interface-controlled synthesis of CeO2(111) and CeO2(100) and their structural transition on Pt(111). Chin. J. Catal. 2019,40 (2), 204-213.
47. Wu, H.; Fu, Q.; Li, Y.; Cui, Y.; Wang, R.; Su, N.; Lin, L.; Dong, A.; Ning, Y.; Yang, F.; Bao, X., Controlled growth of uniform two-dimensional ZnO overlayers on Au(111) and surface hydroxylation. Nano Res. 2019,12 (9), 2348-2354.
48. Song, Y.; Zhou, S.; Dong, Q.; Li, Y.; Zhang, X.; Ta, N.; Liu, Z.; Zhao, J.; Yang, F.; Wang, G.; Bao, X., Oxygen evolution reaction over the Au/YSZ Interface at high temperature. Angew. Chem. Int. Ed. 2019,58 (14), 4617-4621.
49. Song, Y.; Lin, L.; Feng, W.; Zhang, X.; Dong, Q.; Li, X.; Lv, H.; Liu, Q.; Yang, F.; Liu, Z.; Wang, G.; Bao, X., Interfacial enhancement by r-Al2O3 of electrochemical oxidative dehydrogenation of ethane to ethylene in solid oxide electrolysis cells. Angew. Chem. Int. Ed. 2019,58 (45), 16043-16046.
50. Liu, Q.; Huang, W.; Yang, F.; Bao, X., Interface-controlled two-dimensional cuprous oxide structures. Scientia Sinica Chimica 2019,49 (3), 556-563.
51. Li, Y.; Hu, J.; Xu, J.; Zheng, Y.; Chen, M.; Wan, H.; Fu, Q.; Yang, F.; Bao, X., Activation of CO and surface carbon species for conversion of syngas to light olefins on ZnCrOx-Al2O3 catalysts. Appl. Surf. Sci. 2019,494, 353-360.
52. Jin, R.; Peng, M.; Li, A.; Deng, Y.; Jia, Z.; Huang, F.; Ling, Y.; Yang, F.; Fu, H.; Xie, J.; Han, X.; Xiao, D.; Jiang, Z.; Liu, H.; Ma, D., Low temperature oxidation of ethane to oxygenates by oxygen over iridium-cluster catalysts. J. Am. Chem. Soc. 2019,141 (48), 18921-18925.
53. Gan, J.; Luo, W.; Chen, W.; Guo, J.; Xiang, Z.; Chen, B.; Yang, F.; Cao, Y.; Song, F.; Duan, X.; Zhou, X., Mechanistic understanding of size-dependent oxygen reduction actvity and selectivity over Pt/CNT nanocatalysts. Eur. J. Inorg. Chem. 2019,2019 (27), 3210-3217.
54. Cui, X.; Su, H.-Y.; Chen, R.; Yu, L.; Dong, J.; Ma, C.; Wang, S.; Li, J.; Yang, F.; Xiao, J.; Zhang, M.; Ma, D.; Deng, D.; Zhang, D. H.; Tian, Z.; Bao, X., Room-temperature electrochemical water–gas shift reaction for high purity hydrogen production. Nat. Commun. 2019,10 (1), 86.
55. Chen, H.; Wang, R.; Huang, R.; Zhao, C.; Li, Y.; Gong, Z.; Yao, Y.; Cui, Y.; Yang, F.; Bao, X., Surface and subsurface structures of the Pt-Fe surface alloy on Pt(111). J. Phys. Chem. C 2019,123 (28), 17225-17231.
56. Chen, H.; Lin, L.; Li, Y.; Wang, R.; Gong, Z.; Cui, Y.; Li, Y.; Liu, Y.; Zhao, X.; Huang, W.; Fu, Q.; Yang, F.; Bao, X., CO and H2 activation over g-ZnO layers and w-ZnO(0001). ACS Catal. 2019,9 (2), 1373-1382.
57. Zhao, X.; Chen, H.; Wu, H.; Wang, R.; Cui, Y.; Fu, Q.; Yang, F.; Bao, X., Growth of ordered ZnO structures on Au(111) and Cu(111). Acta Phys. -Chim. Sin. 2018,34 (12), 1373-1380.
58. Yang, F.; Liu, Y.; Bao, X., Scanning probe microscopy and nano-spectroscopy. In Modern Methods in Catalysis Research, Xin, Q.; Luo, M.; Xu, J., Eds. Science Press: Beijing, 2018; pp 885-946.
59. Yan, C.; Li, H.; Ye, Y.; Wu, H.; Cai, F.; Si, R.; Xiao, J.; Miao, S.; Xie, S.; Yang, F.; Li, Y.; Wang, G.; Bao, X., Coordinatively unsaturated nickel-nitrogen sites towards selective and high-rate CO2 electroreduction. Energy Environ. Sci. 2018,11 (5), 1204-1210.
60. Liu, Q.; Ning, Y.; Huang, W.; Fu, Q.; Yang, F.; Bao, X., Origin of the thickness-dependent oxidation of ultrathin Cu films on Au(111). J. Phys. Chem. C 2018,122 (15), 8364-8372.
61. Liu, Q.; Han, Y.; Cao, Y.; Li, X.; Huang, W.; Yu, Y.; Yang, F.; Bao, X.; Li, Y.; Liu, Z., In-situ APXPS and STM study of the activation of H2 on ZnO(10-10) surface. Acta Phys. -Chim. Sin. 2018,34 (12), 1366-1372.
62. Liu, Q.; Han, N.; Zhang, S.; Zhao, J.; Yang, F.; Bao, X., Tuning the structures of two-dimensional cuprous oxide confined on Au(111). Nano Res. 2018,11 (11), 5957-5967.
63. Jiang, X.; Li, H.; Xiao, J.; Gao, D.; Si, R.; Yang, F.; Li, Y.; Wang, G.; Bao, X., Carbon dioxide electroreduction over imidazolate ligands coordinated with Zn(II) center in ZIFs. Nano Energy 2018,52, 345-350.
64. Cui, X.; Li, H.; Wang, Y.; Hu, Y.; Hua, L.; Li, H.; Han, X.; Liu, Q.; Yang, F.; He, L.; Chen, X.; Li, Q.; Xiao, J.; Deng, D.; Bao, X., Room-temperature methane conversion by graphene-confined single iron atoms. Chem 2018,4 (8), 1902-1910.
65. Zhao, G.; Yang, F.; Chen, Z.; Liu, Q.; Ji, Y.; Zhang, Y.; Niu, Z.; Mao, J.; Bao, X.; Hu, P.; Li, Y., Metal/oxide interfacial effects on the selective oxidation of primary alcohols. Nat. Commun. 2017,8, 14039.
66. Liu, Y.; Yang, F.; Zhang, Y.; Xiao, J.; Yu, L.; Liu, Q.; Ning, Y.; Zhou, Z.; Chen, H.; Huang, W.; Liu, P.; Bao, X., Enhanced oxidation resistance of active nanostructures via dynamic size effect. Nat. Commun. 2017,8, 14459.
67. Liu, Y.; Yang, F.; Ning, Y.; Liu, Q.; Zhang, Y.; Chen, H.; Bao, X., CO adsorption on a Pt(111) surface partially covered with FeOx nanostructures. J. Energy Chem. 2017,26 (4), 602-607.
68. Liu, Y.; Ning, Y.; Yu, L.; Zhou, Z.; Liu, Q.; Zhang, Y.; Chen, H.; Xiao, J.; Liu, P.; Yang, F.; Bao, X., Structure and electronic properties of Interface-confined oxide nanostructures. ACS Nano 2017,11 (11), 11449-11458.
69. Liu, Q.; Liu, Y.; Li, H.; Li, L.; Deng, D.; Yang, F.; Bao, X., Towards the atomic-scale characterization of isolated iron sites confined in a nitrogen-doped graphene matrix. Appl. Surf. Sci. 2017,410, 111-116.
70. Gao, D.; Zhou, H.; Cai, F.; Wang, D.; Hu, Y.; Jiang, B.; Cai, W.-B.; Chen, X.; Si, R.; Yang, F.; Miao, S.; Wang, J.; Wang, G.; Bao, X., Switchable CO2 electroreduction via engineering active phases of Pd nanoparticles. Nano Res. 2017,10 (6), 2181-2191.
71. Gao, D.; Zhang, Y.; Zhou, Z.; Cai, F.; Zhao, X.; Huang, W.; Li, Y.; Zhu, J.; Liu, P.; Yang, F.; Wang, G.; Bao, X., Enhancing CO2 electroreduction with the metal-oxide interface. J. Am. Chem. Soc. 2017,139 (16), 5652-5655.
72. Chen, H.; Liu, Y.; Yang, F.; Wei, M.; Zhao, X.; Ning, Y.; Liu, Q.; Zhang, Y.; Fu, Q.; Bao, X., Active phase of FeOx/Pt catalysts in low-temperature CO oxidation and preferential oxidation of CO reaction. J. Phys. Chem. C 2017,121 (19), 10398-10405.
73. Cai, F.; Gao, D.; Zhou, H.; Wang, G.; He, T.; Gong, H.; Miao, S.; Yang, F.; Wang, J.; Bao, X., Electrochemical promotion of catalysis over Pd nanoparticles for CO2 reduction. Chem. Sci. 2017,8 (4), 2569-2573.
本组成员 |