李智

时间:2018-03-01浏览:22261设置

李智课题组介绍


课题组长
李智,副教授、研究员
通讯地址:2号楼506B
电子邮件:lizhi@@shanghaitech.edu.cn
ORCID:https://orcid.org/0000-0003-2770-6364
Bilibili:https://space.bilibili.com/1516274974

学术经历:
2002-2006年就读于中国科学技术大学化学系,获学士学位(导师:尤田耙教授)
2006-2011年就读于美国芝加哥大学化学系,获博士学位(导师:Hisashi Yamamoto)
2010-2011 法国波尔多第一大学欧洲化学生物研究所(IECB)访问学生
2011-2014 美国西北大学化学系博士后(导师:Tobin J. Marks)
2015年3月加入上海科技大学物质学院担任助理教授。
2021年11月担任副教授。

所获荣誉:
Distinguished Lectureship Award, Chemical Society of Japan, 2024
中国科学院教育教学成果二等奖,2020
Thieme Chemistry Journal Award, 2018
Reaxys PhD Prize Finalists, Elsevier, 2012
Chateaubriand Scientific Fellowship, the Embassy of France in the US, 2010
高中化学奥林匹克竞赛全国决赛二等奖, 2002

研究介绍

  

催化剂和催化反应是当代化学工业的重要组成部分,催化领域的研究不仅具有基础理论与学术意义、重大的工业应用价值,更可能成为解决当前人类面临的可持续发展问题的关键。在碳中和、可再生资源转化、绿色化工过程和绿色制药化学等新问题的研究过程中,催化剂和催化反应都将起到至关重要的作用。面向这些方向,我们将着力于(1)研究新型路易斯酸催化剂的设计与合成,以及它们在(2)可再生资源转化、塑料降解、(3)有机合成与制药化学中的应用,促进化学工业向绿色可持续方向发展。


本课题组长期诚聘博士后研究员、硕博连读研究生,待遇优厚、课题前沿、工作环境优越,欢迎有志于在有机化学、催化化学等领域开展最先进研究的学生学者加入!有意者请直接与李智邮件联系。



发表论文

Independent Publications:

  1. Zhang, Z.; Gu, H.; Cao, D.-X.; Li, Z.*; Rapid Access to Isoprenoid Quinones through X@RONa-Catalyzed Redox Chain Reaction, J. Am. Chem. Soc. 2024, 146, 29064–29071.

  2. Yao, J.-L.; Li, Z.*; Hafnium(IV)-Salen-Catalyzed Highly Reactive and Enantioselective Epoxidation Directed by Amides, ACS Catal. 2024, 14, 12494–12499.

  3. Luo, Y.-J.; Li, Z.*; Catalytic Hydroxyethylation of Phenols with Renewable Ethylene Glycol Diester as an Alternative to Ethylene Oxide, Eur. J. Org. Chem. 2024, 27, e202400158.

      


  4. Yao, J.-L.; Zhang, Z.; Li, Z.*; Scalable Transition-Metal-Free Synthesis of Aryl Amines from Aryl Chlorides through X@RONa-Catalyzed Benzyne Formation, J. Am. Chem. Soc. 2024, 146, 8839-8846. (Featured in Synfacts and selected as Synfact of the monthSynfacts 2024, 20(07), 0729. Featured in the Organic Chemistry Portal: https://www.organic-chemistry.org/abstracts/lit9/509.shtm)




  5. Luo, Y.-J.; Sun, J.-Y.; Li, Z.*; Rapid chemical recycling of waste polyester plastics catalyzed by recyclable catalyst, Green. Chem. Eng. 2024, 5, 257-265.

      




  6. Wang, T.; Shi, S.; Shi, Y.; Jiang, P.; Hu, G.; Ye, Q.; Shi, Z.; Yu, K.; Wang, C.; Fan, G.; Zhao, S.; Ma, H.; Chang, A. C. Y.; Li, Z.; Bian Q.*; Lin, C.-P.*; Chemical-induced phase transition and global conformational reorganization of chromatin, Nat. Commun. 2023, 14, 5556.

  7. Shi, Z.; Bian, Q.*; Li, Z.*; Access to N-Alkylazaheterocyclic Salts by Activation of Alkoxy C–O Bonds in Polyol Esters, J. Org. Chem. 2023, 88, 9769–9782.




  8. Ding, N.; Li, Z.*; Acid-catalyzed [4+1] dearomatization spiroannulation of hydroquinones and naphthols, Synlett; 2023, 34, 2417-2422. (Special issue dedicated to Prof. H. Yamamoto)



  9. Liu, D.-H.; He, H.-L.; Wang, J.-J.; Zhou, S.-Y.; Zeng, T.; Gao, X.-Y.; Xiao, Y.; Yi, X.; Zheng, A.; Zhang, Y.-B.; Li, Z.*; Acidic metal–organic framework empowered precise hydrodeoxygenation of bio-based furan compounds and cyclic ethers for sustainable fuels, Green. Chem. 2021, 23, 9974-9981.



  10. Xie, W.-B.; Li, Z.*; Bis(μ-oxo)–Dititanium(IV)–Chiral Binaphthyldisulfonate Complexes for Highly Enantioselective Intramolecular Hydroalkoxylation of Nonactivated Alkenes, ACS Catal., 2021, 11, 6270-6275.


  11. Liu, X.; Liu, B.; Shi, Z.; Tan, C.; Fan, R.; Li, Z.; Tan, J.*; Hf(OTf)4-Catalyzed 1,6-Conjugate Addition of 2-Alkyl-azaarenes to para-Quinone Methides, J. Org. Chem. 2021, 86, 3615-3624.

  12. Liu, D.-H.; He, H.-L.; Zhang, Y.-B.; Li, Z.*; Oxidative Aromatization of Biobased Chemicals to Benzene Derivatives through Tandem Catalysis, ACS Sustainable Chem. Eng. 2020, 8, 14322–14329.



  13. Ding, N.; Li, Z.*; When Anthracene and Quinone Avoid Cycloaddition: Acid-Catalyzed Redox Neutral Functionalization of Anthracene to Aryl Ethers, Org. Lett. 2020, 22, 4276-4282. (CBG: https://www.chembeango.com/zixun/50298)


  14. Xie, W.-B.; Li, Z.*; Asymmetric Synthesis of Ethers by Catalytic Alkene Hydro­alkoxy­lation, Synthesis 2020, 52, 2127-2146. (Invited review)


  15. Liu, D.-H., Marks, T. J.; Li, Z.*; Catalytic One-Pot Conversion of Renewable Platform Chemicals to Hydrocarbon and Ether Biofuels via Tandem Hf(OTf)4 + Pd/C Catalysis, ChemSusChem 2019, 12, 5217-5223. (Cover Feature: ChemSusChem 2019, 12, 5214.)



  16. Liu, H.; Zhu, Y.-L.; Li, Z.*; Catalytic amidation of natural and synthetic polyol esters with sulfonamides, Nat. Commun. 2019, 10, 3881. (自然科学基金委科学传播中心: http://www.nsfc.gov.cn/csc/20340/20343/45548/; 科学网: http://news.sciencenet.cn/sbhtmlnews/2019/10/350000.shtm)

      


  17. Xu, X.-L.; Li, Z.*; Catalytic Redox Chain Ring Opening of Lactones with Quinones To Synthesize Quinone-Containing Carboxylic Acids; Org. Lett., 2019, 21, 5078-5081. (CBG: https://www.chembeango.com/zixun/43665)


  18. Xu, X.-L.; Li, Z.*; Deciphering the Redox Chain Mechanism in the Catalytic Alkylation of Quinones; Synlett, 2018, 29, 1807-1813. (Invited Synpact article)


  19. Xu, X.-L.; Li, Z.* Catalytic Electrophilic Alkylation of p-Quinones through a Redox Chain Reaction; Angew. Chem. Int. Ed., 2017, 56, 8196–8200. (Top 3 Most Accessed Communications of June 2017; X-MOL: http://www.x-mol.com/news/8483)



PhD & Postdoc publications:

1.  Lohr, T. L.; Li, Z.; Marks, T. J.* Thermodynamic Strategies for C–O Bond Formation and Cleavage via Tandem Catalysis; Acc. Chem. Res.201649 (5), pp 824–834.

2.  Lohr, T. L.; Li, Z.; Assary, R. S.; Curtiss, L. A.; Marks, T. J.* Mono- and tri-ester hydrogenolysis using tandem catalysis. Scope and mechanism; Energy Environ. Sci.2016, 9 (2), pp 550–564. 

3.  Lohr, T. L.; Li, Z.; Marks, T. J.* Selective Ether/Ester C–O Cleavage of an Acetylated Lignin Model via Tandem Catalysis; ACS Catal.20155 (11), pp 7004–7007. 

4.  Lohr, T. L.†; Li, Z.†; Assary, R. S.; Curtiss, L. A.; Marks, T. J.* Thermodynamically Leveraged Tandem Catalysis for Ester RC(O)O–R′ Bond Hydrogenolysis. Scope and Mechanism; ACS Catal.,20155 (6), pp 3675–3679. (Equal contribution) 

5.  Li, Z.; Assary, R. S.; Atesin, A. C.; Curtiss, L. A.; Marks, T. J.* Rapid Ether and Alcohol C-O Bond Hydrogenolysis Catalyzed by Tandem High-valent Metal Triflate + Supported Pd Catalysts; J. Am. Chem. Soc., 2014136, 104-107. 

6.  Assary, R. S.*; Atesin, A. C.; Li, Z.; Curtiss, L. A.*; Marks, T. J.* Reaction Pathways and Energetics of Etheric C–O Bond Cleavage Catalyzed by Lanthanide Triflates; ACS Catal.20133, 1908–1914. 

7.  Olivares-Romero, J. L.; Li, Z.; Yamamoto, H.* Catalytic Enantioselective Epoxidation of Tertiary Allylic and Homoallylic alcohols; J. Am. Chem. Soc.2013135, 3411-3413. 

8.  Li, Z.; Yamamoto, H.* Hydroxamic Acids in Asymmetric Synthesis; Acc. Chem. Res.,2013,46, 506-518.

9.  Olivares-Romero, J. L.; Li, Z.; Yamamoto, H.*; Hf(IV)-Catalyzed Enantioselective Epoxidation of N-Alkenyl Sulfonamides and N-Tosyl Imines; J. Am. Chem. Soc.2012134, 5440-5443. (Top 20 Most Read Articles of March 2012

10.  Li, Z.; Yamamoto, H.*; Zirconium(IV)- and Hafnium(IV)-Catalyzed Highly Enantioselective Epoxidation of Homoallylic and Bishomoallylic Alcohols; J. Am. Chem. Soc. 2010132, 7878-7880. 

11.  Li, Z.; Zhang, W.; Yamamoto, H.*; Vanadium-Catalyzed Enantioselective Desymmetrization of meso-Secondary Allylic Alcohols and Homoallylic Alcohols; Angew. Chem. Int. Ed., 2008, 47, 7520-7522; Angew. Chem., 2008,120, 7630-7632.


本组成员

叶雨萌

19级研究生    上海科技大学学士

邮箱:yeym@@shanghaitech.edu.cn


谷欢潮

21级研究生    上海科技大学学士

邮箱:guhch@@shanghaitech.edu.cn

张佳怡

21级研究生    南开大学学士

邮箱:zhangjy5@@shanghaitech.edu.cn

万远鼎

22级研究生    南昌大学学士

邮箱:wanyd2022@@shanghaitech.edu.cn

刘晨旭

22级研究生    大连理工大学学士

邮箱:liuchx2022@@shanghaitech.edu.cn

汪亦扬

22级研究生    上海科技大学学士

邮箱:wangyy12022@@shanghaitech.edu.cn

张诗倩

23级研究生    浙江工业大学学士

邮箱:zhangshq2023@@shanghaitech.edu.cn



罗思弘

24级研究生    上海科技大学学士

邮箱:luosh2024@@shanghaitech.edu.cn

徐三钦

24级研究生    上海科技大学学士

邮箱:xusq2024@@shanghaitech.edu.cn

姚羽泽

21级本科生

邮箱:yaoyz@@shanghaitech.edu.cn



过往成员在组学位/职位在组年份离组去向
刘华博士后2015-2019上海科技大学分析测试中心
Alain You Li博士后2022-2023Clariant
徐小龙博士2015-2020桑迪亚医药技术(上海)有限责任公司
刘东煌博士2015-2020南方科技大学化学系博士后
丁楠博士2016-2021宁波康龙化成公司
谢文斌博士2016-2021中国科学院大学本部
师展博士2018-2023南京三迭纪
姚嘉麟博士2018-2024上海簇睿低碳能源技术有限公司
罗雨季博士2019-2024中国科学院上海有机化学研究所博士后
张晓洁硕士2015-2017上海睿智化学
李舒婷硕士2019-2022University of Strasbourg
蒋佳晨硕士2020-2023毕得医药
刘宏研究生2015-2017上海科技大学
童敬庸研究生2017-2019
王彦昆研究生2020-2022
王娇娇本科生/科研助理2016-2019Michigan State University
祝亿灵本科生/科研助理2018-2019Boston College
唐一丰本科生2017-2019The University of Chicago
印思泳本科生2017-2019中国科学院上海有机化学研究所
Eric Yang暑期访问生2019The University of Chicago
康逸飞
本科生2019-2020
沈昊
本科生2019-2020
Baylor University
张子宁本科生2018-2021The University of Chicago
孙嘉寅本科生2018-2021京都大学
曹敦旭本科生2020-2022中国科学技术大学
赵怡临
本科生2021-2023中国科学院古脊椎动物与古人类研究所
葛逸飞本科生2021-2024Universit of Illinois, Urbana & Champaign
欧阳坤辰本科生2021-2024北京大学


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