任毅

时间:2022-04-12浏览:25097设置

主族元素功能材料化学实验室


课题组长


 

任毅    上海市特聘教授/博士生导师                                      

通讯地址:物质学院2号楼406D

电子邮件:renyi@shanghaitech.edu.cn

Websitehttps://yiren2018.wordpress.com/ 

               https://orcid.org/0000-0003-4245-5647

2018年1月 - 现在   助理教授     上海科技大学物质科学与技术学院

2017年2月 - 2017年12月  博士后   美国宾夕法尼亚州立大学化学系

2016年2月 - 2017年1月    博士后   美国罗格斯大学化学系

2012年6月 - 2015年1月   博士后    美国普林斯顿大学化工系

2007年9月 - 2012年4月    博士       加拿大卡尔加里大学


所获荣誉


2023       Thieme Chemistry Journal Award

2019       Shanghai Eastern Scholar

2012       PCCM-MRSEC Postdoctoral Fellowship, Princeton University

               https://pccm.princeton.edu/people/alumni

2012       Chinese Government Award for Outstanding Self-Financed Students Abroad 

2012       Graduate Student Travel Award, University of Calgary

2011       Talisman Energy Graduate Scholarship in Energy & Related Studies, Alberta 

2011       Graduate Faculty Council Scholarship - Doctoral 

2008       Alberta Ingenuity Graduate Student Scholarship in Nanotechnology, Alberta 

2007       Excellent Graduate Student, Jilin University


研究介绍


研究方向:有机功能材料化学元素有机合成化学 、高分子化学与物理

本课题组以构建“新型光电材料”为导向,以“主族元素”有机合成化学为基础,探索“新型光电材料”在能源材料领域中的潜在应用。主要研究内容包括:

有机合成化学/高分子合成化学:开发新颖“杂原子-(X-C) 的成键方式,用于制备含“硼、氮、磷、硫”等主族元素的小分子、超分子、高分子聚合物。

有机材料化学与物理:设计并合成含“硼、氮、磷、硫”等主族元素的新颖结构单元;确定其化学结构-物理性质-器件功能之间关系,探索如何利用“主族元素” 调节、优化材料的光电学、磁学、力学性质的规律

材料化学与物理:利用“主族元素”独特的化学结构和电子结构,开发自组装杂化纳米材料,并应用于柔性电子器件。



组内信息


本课题组长期诚聘博士后研究员、硕博连读研究生,待遇优厚,工作环境优越,欢迎有志于在有机化学、高分子化学、材料化学等领域开展最前沿研究的学生、学者加入!有意者请直接与任毅邮件联系。

2019:   杨凯        上海科技大学研究生优秀学生

2021:梓        上海科技大学研究生优秀学生

2022:   薛策策     中国科学院大学三好学生

2022:   李灿         研究生国家奖学金(2万奖学金)

2023:李灿         上海科技大学优秀毕业生

2023:刘赵欣      Student Travel Award (会议奖金) 24th International Conference on Phosphorus Chemistry


发表论文



Independent Publications:

  

52. Narrow-Band Emitting Character of New Organophosphorus Materials. to be Submitted


51. Porous Organic Polymer Containing Active Boron Element: Synthesis, Characterizations, and Applications. Invited Review.


50. Designing Adaptable Molecular Motors via P-N and P-C Chemistry.  Zhaoxin Liu, Chao Li, Zi Yang, Yi Ren*. to be Submitted.


49. Heteroatom-Azulene Embeded Polycyclic Aromatic Hydrocarbons: Synthesis, Photophysics, and the Persistent Radical Cations. Can Li,# Wei Zhou,# Zhaoxin Liu,# Rong Gao, Zhijun Ning*Yi Ren*. to be Submitted


48. Boronium Based Polythiophene Networks for Visible-Light-Driven Hydrogen EvolutionXue Han, Boyan Zhang, Na Yu, Min Peng, Haiming Liu, Guijun Ma*, Yi Ren*. to be Submitted.


47. Design of Indole-Functionalized Phosphepines towrds New Organic Chromophoes. Zhaoxin Liu, Yi Ren, Synlett. 2024Invited Article, DOI: 10.1055/a-2214-7484.


46. Amorphous Porous Organic Polymers Containing Main Group ElementsZhikai Zhang#, Zhaoxin Liu#, Cece Xue#, Hongyi Chen, Xue Han, Yi Ren*. Communications ChemistryInvited Review, 2023, accepted. 2023 Editors' Highlights


45. Synthesis and Photophysical Properties of Carbazole-Functionalized Diazaphospepines via Sequent P-N ChemistryXinyu Li, Zhaoxin Liu, Can Li, Yanpeng Qi, Yi Ren*. J. Org. Chem. 202388, 13678-13685.

44. Synthesis and Characterizations of Polythiophene Networks via Nonplanar BN Lewis Pair Building BlocksXue Han, Cece Xue,Zhou Zhao,  Min Peng, Qing, Wang, Haiming Liu, Na Yu, Chaodan Pu*, Yi Ren*, ACS Macro Letters, 2023, 12, 961-967.

43. Synthesis, Post-Functionalization, and Photoluminescence Properties of Contorted Diazaphosphepine-Based Polycyclic Aromatic Hydrocarbons. Can Li,  Kai Yang, Xinyu Li, Shuya Wen, Yi Ren*. Dalton Trans.2023, 52, 9294-9300.


42. Investigation of Excited State Intramolecular Proton Transfer and Structural Dynamics in Bis-benzimidazole Derivative (BBM) Using Femtosecond Stimulated Raman SpectroscopyJunhan Xie, Ziyu Wang, Jiaming Jiang, Ruixue zhu, Tsu-Chien Weng, Yi Ren, Shuhua Han, Yifan Huang, Weimin Liu. Int. J. Mol. Sci. 2023, 24, 9438

41. Stille Type PCoupling Polycondensation towards PhosphorusCrosslinked Polythiophenes with P-Regulated Photocatalytic Hydrogen EvolutionZhikai Zhang, Boyang Zhang, Xue Han, Hongyi Chen, Guijun Ma,* Yi Ren*. Chem. Sci. 202314, 2990-2998.

40. Synthesis and Unecxpected Optical Properties of Ionic Phosphosrus Heterocycles with P-Regulated Non-Covalent InteractionsZi Yang, Xinyu Li, Kai Yang, Na Yu, Rong Gao, and Yi Ren*. J. Org. Chem. 2023, 882792-2800. 

39. Facile Route to Novel Diazaphosphinine-Based Polycyclic Aromatic HydrocarbonsZi Yang, Can Li, Xingchen Liu, Xinyu Li, Na Yu, and Yi Ren*. Angew. Chem. Int. Ed. 2022, 10.1002/anie.202212844.

@https://www.shanghaitech.edu.cn/eng/2022/1031/c1260a947951/page.htm

@https://www.shanghaitech.edu.cn/2022/1011/c1001a901011/page.htm

38. Ultramicroporous Organophosphorus Polymers via Self-Accelerating PC Coupling Reaction: Kinetic Effects on Crosslinking Environments and Porous StructuresZhikai Zhang, Qi Wang, Haiming Liu, Tao Li, and Yi Ren*. J. Am. Chem. Soc. 202214411748-11756.

@https://www.shanghaitech.edu.cn/2022/0702/c1001a665464/page.htm


37. Conjugated Boron Porous Polymers Having Strong p-π* Conjugation for Amine Sensing and AbsorptionCece Xue, Min Peng, Zhikai Zhang, Xue Han, Qing Wang, Conger Li, Haiming Liu, Tao Li, Na Yu, Yi Ren*. Macromolecules,2022,553850-3859.

36. Tailored Solvatochromic NIR Phosphorus-Chromophores via Selective P-N and P-C Chemistry in P-Heteropines. Zi Yang, Xinyu Li, Kai Yang, Zhikai Zhang, Yankun Wang, Thomas Baumgartner, and Yi Ren*. Org. Lett. 2022, 24, 2045-2049.

35. Excited-State Engineering of Oligothiophenes via Phosphorus Chemistry towards Strong Fluorescence Materials. Zi Yang, Zhikai Zhang, CeCe Xue, Kai Yang, Rong Gao, and Yi Ren*. Phys. Chem. Chem. Phys. 2021, 23, 24265-24272.

34. A Multiple Excited State Engineering of Boron-Functionalized Diazapentance via Tuning of Molecular Orbital CouplingZi Yang, Kai YangX. Wei, Wei Liu, Rong Gao, Frieder Jaekle, Yueh-Lin. Loo, and Yi Ren*. J. Phys. Chem. Lett. 202138, 9308-9314.

33. Highly Compact Nanochannel Thin Films with Exceptional Thermal Conductivity and Water Pumping for Efficient Solar Steam Generation.

W. Wei, Q. Guan, C. You, J. Yu, Z. Yuan, P. Qiang, C. Zhou, Y. Ren, Z. You, F. Zhang. J. Mater. Chem. A 20208, 13927. 


32. Hybrid Polyphosphazene-Organosilicon Polymers as Useful Elastomers.

C. Tong, S. McCarthy, Z. Li, J. Guo, Q. Li, C. N. Pacheco, Y. Ren, H. R. Allcock. ACS Applied Polymer Materials 20197, 1881.


31. Polyphosphazenes and Cyclotriphosphazenes with Propeller-Like Tetraphenylethyleneoxy Side Groups: Tuning Mechanical and Optoelectronic Properties

Y. Ren, K. Yang, D. Shan, C. Tong, H. R. Allcock. Macromolecules20185, 5011


30. Molecular Engineering of Polyphosphazenes and SWNT Hybrids with Potential Applications as Electronic Materials.

 Y. Ren, Z. Li, H. R. Allcock. Macromolecules20185, 5011. 


29. p-π Conjugated Polymers Based on Stable Triarylborane with n-Type Behavior in Optoelectronic Devices.

B. Meng, Y. Ren, J. Liu, F. Jäkle, L. Wang. Angew. Chem. Int. Ed. 2018, 8, 2183.


28. Incorporation of Group 13 Elements into Polymers, “Main Group Strategies towards Functional Hybrid Materials”.2018 John Wiley & Sons Lt.

 Y. Ren, F. Jäkle.

 

27. Hybrid conjugated polymers with alternating dithienosilole or dithienogermole and tricoordinate boron units. 

Adachi, Y. Ooyama, Y. Ren, X. Yin, F. Jäkle, J. Ohshita. Polym.Chem. 2018, 10.1039/C7PY01790A. 


Selected PhD & Postdoc Publications:

26. Pyridalthiadiazole acceptor-functionalized triarylboranes with multi-responsive optoelectronic characteristics. 

X. Yin#, K. Liu#, Y. Ren, R. A. Lalancette, Y.-L. Loo, F. Jäkle, Chem. Sci. 20178, 5497.


25. [d]-Carbond-Carbon Double Bond Engineering in Diazaphosphepines: Modulating the Chemical and Electronic Structures of Heteropines. 

Y. Ren, M. Sezen, F. Gao, F. Jäkle, Y.-L. Loo. Chem. Sci. 20168, 5497.


24. Cooperative Self-Assembly of Phosphole-Lipids and SWCNTs. 

Y. Ren, J. Gao, A. Hailey, T. Baumgartner, Y.-L. Loo, Chem. Mater. 2016, 28, 8407.


23. Bio-inspired Phosphole-Lipids: From Highly Fluorescent Organogels to Mechanically Responsive FRET. 

Y. Ren, W. H. Kan, V. Thangadurai, T. Baumgartner. Angew. Chem. Int. Ed. 2012, 51, 3964. (Highlighted in the issue of the Canadian Chemical News, June 2012)


22. External-Stimuli Responsive Photophysics and Liquid Crystal Properties of Self-Assembled “Phosphole-Lipids”. 

 Y. Ren, W. H. Kan, M. A. Henderson, P. G. Bomben, C. P. Berlinguette, V. Thangadurai, T. Baumgartner. J. Am. Chem. Soc. 2011, 133, 17014.(Highlighted in “Noteworthy Chemistry” Dec. 2011).


21. Dually Switchable Heterotetracenes: Addressing the Photophysical Properties and Self-Organization of the P-S System.

Y. Ren, T. Baumgartner. J. Am. Chem. Soc. 2011, 133, 1328.


20. Merging Thiophene with Boron: New Building Blocks for Conjugated Materials. 

Y. Ren, F. Jäkle. Dalton Trans. 2016, 45, 13996.


19. A Structure-Property Study Toward π-Extended Phosphole Chromophores with Ambipolar Redox Properties. 

Y. Ren, T. Baumgartner. Can. J. Chem. 2016, 94, 297.


18. Self-Assembly of Axially Functionalized Subpthalocyanines in Thin Films. 

Y. Ren, A. M. Hiszpanski, Y.-L. Loo. Chem. Mater. 2015, 27, 4008.


17. Isoindigo-Containing Small Molecules for Organic Solar Cells: Effect of Backbone Extension on Photophysics, Molecular Organization, and Device Performance. 

Y. Ren, A. Hailey, A. M. Hiszpanski, Y.-L. Loo. Chem. Mater. 2014, 26, 6570.


16. Fluorinated and Hydrogenated Self-Assembled Monolayers (SAMs) on Anodes: Effects of SAM Chemistry of Devices Characteristics of Polymer Solar Cells. 

H. Wang, J. M. MativetskyY. Ren, E. D. Gomez, E. D.; C. Jaye, J. Schwartz, D. A. Fischer, Y.-L. Loo. Org. Electron. 201415, 3333.


15. Structure-Property Relationship Study of Substitution Effects on Isoindigo-Based Model Compounds as Electron Donors in Organic Solar Cells. 

Y. Ren, A. M. Hiszpanski, L. Whittaker-Brooks, Y.-L. Loo. ACS Appl. Mater. Interfaces, 2014, 6, 14533.


专利

1.一种三芳基硼类共轭聚合物多孔材料及其制备方法和用途, 2021.

2. 一种具有强电荷分离的含硼高分子材料的制备及用于光催化水产氢应用, 2022.

3. 一种三价有机磷化合物的合成方法, 2022.


教授课程



普通化学(I), 3学时, 冬季学期

主族元素化学, 2学时, 冬季学期



本组成员


李心宇(2020), 武汉理工大学 (方向:柔性六元磷共轭分子的合成与光物理性质研究)

李灿(2020), 上海师范大学 (方向:七元磷多环芳香烃的合成与光物理性质研究)

韩雪(2020), 郑州大学 (方向:有机硼-氮高分子材料的合成与光催化理性质研究)

刘赵欣(2021), 青岛科技大学 (方向:有机磷分子马达材料的合成与光理性质研究)

陈弘毅(2021), 郑州大学 (方向:磷-碳偶联在高分子材料的应用与光理性质研究)

赵柯煊(2022), 北京化工大学 (方向:有机硼高分子材料的合成与电致变色

张济(2023), 上海科技大学 (方向:刚性磷共轭分子的合成与光物理性质研究)

李超(2023), 皖西学院 (方向:有机磷共轭分子的合成与光物理性质研究)

HALL OF FAME

杨凯(2017), 中山大学 (方向:硼-氮共轭分子的合成与光物理性质研究)

葛帅丽(2019), 陕西师范大学 (方向:有机磷共轭分子的合成与光物理性质研究)

薛策策(2018), 郑州大学 (方向:有机硼高分子荧光材料的合成与有害物质检测性质研究)

扬梓(2018), 郑州大学 (方向:六元磷共轭材料的合成与光理性质研究)

张志凯(2019), 大连理工大学 (方向:磷-碳偶联在多孔高分子材料的应用)

王燕华(2020), 常州大学 (方向:六元磷共轭材料的合成与光理性质研究)


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