林柏霖课题组介绍

  课题组长  
林柏霖,助理教授、研究员
通讯地址:
电子邮件:linbl@@shanghaitech.edu.cn
中国科学技术大学化学系学士,导师郭庆祥教授,方向有机化学和计算化学。本科毕业之后于美国加州理工学院(California Institute of Technology)化学与化工系读取博士学位,导师John E. Bercaw教授,方向金属有机化学。主要研究内容为发展新的钯和铂络合物,活化包括甲烷、苯及烯烃等不含杂原子的有机分子C-H键,并研究其机理。博士毕业之后在美国斯坦福大学(Stanford University)化学系从事博士后研究,主要研究对象包括铜蛋白的无机小分子模拟、二氧化碳电化学还原以及二氧化碳衍生的自修复高分子硅胶材料。2013年12月加入上海科技大学物质科学与技术学院,任助理教授。
  研究兴趣  
以能源或材料领域里面一些重大问题为导向,结合计算化学与实验化学,在金属有机基元反应的基础上,发展新的催化体系和方法,并研究其机理。具体包括三个方向:1、发展以二氧化碳电化学还原为基础的人工光合作用系统,探索新的储能与减排方式;2、发展新的分子催化剂,以二氧化碳为可再生碳来源,合成高附加值的有机分子;3、发展新的催化方法,以二氧化碳为原材料,合成新的高分子材料。 
  发表文章  
Independent:
1. Chi Fang (Co-first Author), Chunlei Lu (Co-first Author), Muhua Liu, Yiling Zhu, Yao Fu*, Bo-Lin Lin*. "Selective Formylation and Methylation of Amines Using Carbon Dioxide and Hydrosilane Catalyzed by Alkaline Metal Carbonates"ACS Catal. 2016, 6, 7876-7881.(Monthly most-read list)

2. Muhua Liu (Co-first Author), Tian Qin (Co-first Author), Qingqing Zhang (Co-first Author), Chi Fang (Co-first Author), Yao Fu, Bo-Lin Lin*. "Thermal Reductive Transformations of Carbon Dioxide Catalyzed by Small Molecules Using Earth-Abundant Elements" Sci. China Chem. 2015, 58, 1524-1531 (invited review).
 
Pre-independent (selected):
1. Andrew M. Thomas (Co-first author), Bo-Lin Lin (Co-first author), Erik C. Wasinger, T. Daniel P. Stack*. "Ligand Non-innocence of Thiolate/Disulfide in Dinuclear Copper Complexes: Solvent-Dependent Redox Isomerization and Proton-Coupled Electron Transfer" J. Am. Chem. Soc., 2013, 135, 18912-18919.

2. Bo-Lin Lin, Peng Kang, T. Daniel P. Stack*. “Unexpected Ccarbene-X (X: I, Br, Cl) Reductive Elimination from N-Heterocyclic Carbene Copper Halide Complexes Under Oxidative Conditions” Organometallics, 2010, 29, 3683-3685.

3. Bo-Lin Lin, Koyel X. Bhattacharyya, Jay A. Labinger*, John E. Bercaw*. “Competitive Benzene C-H Bond Activation versus Olefin Insertion in a (Monomethyl)palladium(II)β-Diketiminate Complex” Organometallics, 2009, 28, 4440-4405.

4. John E. Bercaw*, George S. Chen, Jay A. Labinger*, Bo-Lin Lin (Co-first author,alphabetically ordered) “Hydrogen Tunneling in Protonolysis of Platinum(II) and Palladium(II) Methyl Complexes: Mechanistic Implications” J. Am. Chem. Soc., 2008, 130, 17654-17655. 

5. Bo-Lin Lin, Lei Liu*, Yao Fu, Shi-Wei Luo, Qian Chen, Qing-Xiang Guo*. “Comparing Nickel- and Palladium-Catalyzed Heck Reactions” Organometallics, 2004, 23, 2114-2123. (4th most-accessed article in Organometallics, 2004.) 
  本组成员