米启兮

米启兮课题组介绍

米启兮，助理院长、副教授、研究员
通讯地址：物质学院5号楼205D
电子邮件：miqx@@shanghaitech.edu.cn
个人简历：
1999–2003北京大学化学学院应用化学专业、计算机辅修专业，理学学士
2003–2009美国西北大学化学系化学专业，哲学博士
2009−2012美国加州理工学院化学系博士后
2013至今上海科技大学物质学院课题组长、博士生导师

研究介绍

米启兮从美国西北大学化学系毕业后，在加州理工学院太阳能化学创新中心(CCI Solar)进行了博士后研究，并与美国能源部下属的阿贡-西北太阳能研究中心(ANSER)和人工光合作用联合中心(JCAP)开展了紧密合作。米启兮课题组主要研究方向为材料物理化学和新型光电转化材料，尤其是卤化锡钙钛矿材料，围绕新型半导体材料的理论建模计算、材料合成与晶体结构表征、单晶生长与薄膜制备、体相和表界面缺陷抑制、器件性能优化提升各个方面展开。在近5年中，对无铅钙钛矿（尤其是锡卤化物）材料的成分–结构–物性关系及潜在的应用方向开展了系统研究，突破了本领域固有看法的束缚，锡钙钛矿太阳电池器件性能达到国际领先水平。

本课题组长期招收博士后研究员和硕博连读研究生，有意者请邮件联系。

发表论文

Walter, M. G.; Warren, E. L.; McKone, J. R.; Boettcher, S. W.; Mi, Q.; Santori, E. A.; Lewis, N. S. Solar Water Splitting Cells. Chem. Rev. 2010, 110, 6446–6473.
Mi, Q.; Zhanaidarova, A.; Brunschwig, B. S.; Gray, H. B.; Lewis, N. S. A Quantitative Assessment of the Competition between Water and Anion Oxidation at WO₃ Photoanodes in Acidic Aqueous Electrolytes. Energy Environ. Sci. 2012, 5, 5694–5700.
Mi, Q.; Ping, Y.; Li, Y.; Cao, B.; Brunschwig, B. S.; Khalifah, P. G.; Galli, G. A.; Gray, H. B.; Lewis, N. S. Thermally Stable N₂-Intercalated WO₃ Photoanodes for Water Oxidation. J. Am. Chem. Soc. 2012, 134, 18318–18324.
Mi, Q.; Coridan, R. H.; Brunschwig, B. S.; Gray, H. B.; Lewis, N. S. Photoelectrochemical Oxidation of Anions by WO₃ in Aqueous and Nonaqueous Electrolytes. Energy Environ. Sci. 2013, 6, 2646–2653.
Liao, Y.; Liu, H.; Zhou, W.; Yang, D.; Shang, Y.; Shi, Z.; Li, B.; Jiang, X.; Zhang, L.; Quan, L. N.; Quintero-Bermudez, R.; Sutherland, B. R.; Mi, Q.; Sargent, E. H.; Ning, Z. Highly Oriented Low-Dimensional Tin Halide Perovskites with Enhanced Stability and Photovoltaic Performance. J. Am. Chem. Soc. 2017, 139, 6693–6699.
Shi, Z.; Zhang, Y.; Cui, C.; Li, B.; Zhou, W.; Ning, Z.; Mi, Q. Symmetrization of the Crystal Lattice of MAPbI₃ Boosts the Performance and Stability of Metal–Perovskite Photodiodes. Adv. Mater. 2017, 29, 1701656.
Li, B.; Long, R.; Xia, Y.; Mi, Q. All-Inorganic Perovskite CsSnBr₃ as a Thermally stable, Free-Carrier Semiconductor. Angew. Chem. Int. Ed. 2018, 57, 13154–13158.
Li, B.; Long, R.; Yao, Q.; Zhu, Z.; Mi, Q. Band Alignment Boosts Charge-Carrier Collection in Sn-based Perovskite over Pb Counterparts. J. Phys. Chem. Lett. 2019, 10, 3699−3703.
Wu, Z.; Zhang, Q.; Li, B.; Shi, Z.; Xu, K.; Chen, Y.; Ning, Z.; Mi, Q. Stabilizing the CsSnCl₃ Perovskite Lattice by B Site Substitution for Enhanced Light Emission. Chem. Mater. 2019, 31, 4999−5004.
Shi, Z.; Fang Z.; Wu J.; Chen Y.; Mi, Q. Order–disorder transition of a rigid cage cation embedded in a cubic perovskite. Nat. Commun. 2021, 12, 3548.
Zhu Z.; Mi, Q. Substituted thiourea as versatile ligands for crystallization control and surface passivation of tin–based perovskite. Cell Reports Physical Science 2022, 3, 100690.
Zhu Z.; Jiang X.; Yu D.;Yu N.; Ning Z.; Mi, Q. Smooth and Compact FASnI₃Films for Lead-Free Perovskite Solar Cells with over 14% Efficiency. ACS Energy Lett. 2022, 7, 2079–2083.
Wang, Q.; Bai, F.-Y.; Wang, Y.; Niu, F.; Zhang, Y.; Mi, Q.; Hu, K.; Pan, X.* Photoinduced Ion-Pair Inner-Sphere Electron Transfer-Reversible Addition-Fragmentation Chain Transfer Polymerization, J. Am. Chem. Soc., 2022, 144, 19942–19952.
Shi, Y.; Zhu, Z.; Miao, D.; Ding, Y.; Mi, Q. Interfacial Dipoles Boost Open-Circuit Voltage of Tin Halide Perovskite Solar Cells. ACS Energy Lett. 2024, 9, 1895–1897.
Zhang, C.; Yu, J.; Cui, Y.*; Lue, Y.; Zhang, Y.; Gao, T.; He, Y.; Chen, X.; Li, T.; Lin, T.; Mi, Q.; Yu, Y.; Liu, W.* An electron-blocking interface for garnet-based quasi-solid-state lithium-metal batteries to improve lifespan. Nat. Commun., 2024, 15, 5325.
Sun, Z.; Hong, C.; Chen, Y.; Sheng, Z.; Wu, S.; Wang, Z.; Liang, B.; Liu, W.-T.; Yuan, Z.; Wu, Y.; Mi. Q.; Liu, Z.; Shen, J.; Wu, S.* Resolving and routing the magnetic polymorphs in 2D layered antiferromagnet. Nat. Mater., 2025, 24, 226–233.
Miao, D.; Zhu, Z.; Ding, Y.; Ning, Q.; Cheng, L; Fang, Z.; Chen, Y.; Qin, G.; Shi, Y.; Li, G.; Mi, Q.* Congruent and Oriented Crystallization of Mixed Sn–Pb Perovskite from the Nano- to Centimeter Scale. Adv. Sci., 2025, 2412101.